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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Clément, Sébastien
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2020Phosphonium‐based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self‐assembly and photovoltaic performancescitations
- 2020High-pressure, high temperature synthesis of a mesoporous α-quartz/bismuth nanowire compositecitations
- 2020Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
- 2019Synthesis, characterization and modeling of self-assembled porphyrin nanorodscitations
- 2019High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1citations
- 2017A self-assembly toolbox for thiophene-based conjugated polyelectrolytes: surfactants, solvent and copolymerisationcitations
- 2017A self-assembly toolbox for thiophene-based conjugated polyelectrolytes: surfactants, solvent and copolymerisation.
- 2016High-Permittivity Conjugated Polyelectrolyte Interlayers for High-Performance Bulk Heterojunction Organic Solar Cellscitations
- 2016Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with pi-extended porphyrinscitations
- 2014A facile synthesis of proton-conducting organic-inorganic membranescitations
- 2014Synthesis of TiO2-poly(3-hexylthiophene) Hybrid Particles through Surface-Initiated Kumada Catalyst-Transfer Polycondensationcitations
- 2012Synthesis and characterization of carboxystyryl end-functionalized poly(3-hexylthiophene) / TiO2 hybrids in view of photovoltaic applicationscitations
- 2010Synthesis and characterization of nanocomposites based on functional regioregular poly(3-hexylthiophene) and multiwall carbon nanotubescitations
- 2009In situ high pressure and high temperature Raman studies of (1-x)SiO2xGeO2 glassescitations
Places of action
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article
High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1
Abstract
A silicalite-1/bismuth composite was synthesized by insertion of liquid bismuth in the 5.5 Å diameter pores of the zeolite under high-pressure, high-temperature conditions. The insertion of bismuth stabilizes the structure with respect to pressure-induced amorphization. Transmission electron microscopy indicated the presence of chains of atoms, which correspond to the 5.5 Å diameter of the host silicalite-1 structure. Neutron powder diffraction also confirmed the insertion of Bi in the pores of silicalite-1. Density functional theory calculations indicate that the insertion of bismuth results in formation of chains with short and long Bi-Bi distances in the pores of the host silicalite-1 linked to the framework by van der Waal's interactions. The material is predicted to be a semiconductor with a band gap of 0.4 eV.