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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Malinowska, Elżbieta
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2020Promising electrodeposited biocompatible coatings for steel obtained from polymerized microemulsionscitations
- 2019Directly-thiolated graphene based electrochemical sensor for Hg(II) ioncitations
- 2017Graphene Nanoplatelets for Screen-Printed Nonenzymatic Voltammetric H2O2 Sensorscitations
- 2015Electrochemical oligonucleotide-based biosensor for the determination of lead ioncitations
- 2013Development of silicon-based electrochemical transducerscitations
- 2013Oligonucleotide-Based Electrochemical Biosensor for Hg2+ Using Methylene Blue as a Redox Indicatorcitations
- 2009Influence of inner transducer properties on EMF response and stability of solid-contact anion-selective membrane electrodes based on metalloporphyrin ionophorescitations
- 2009New polyacrylate-based lead(II) ion-selective electrodescitations
- 2007Further studies on the role of redox-active monolayer as intermediate phase of solid-state sensorscitations
- 2006CMP(O) tripodands: Synthesis, potentiometric studies and extractionscitations
- 2005Studies on ferrocene organothiol monolayer as an intermediate phase of potentiometric sensors with gold inner contactcitations
- 2004Design of ferrocene organothiol monolayer as intermediate phase for miniaturized electrochemical sensors with gold contact
- 2004Towards advanced chemical microsensors—an overviewcitations
- 2004Polymeric membrane electrodes with enhanced fluoride selectivity using Zr(IV)-porphyrins functioning as neutral carrierscitations
Places of action
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article
Further studies on the role of redox-active monolayer as intermediate phase of solid-state sensors
Abstract
The aim of this work was to further study the impact of polyacrylate membrane and the self assembled monolayer (SAM) on the elimination of CO2 interferences in solid-state ion-selective sensors with gold internal electrode. For this purpose permeability to CO2 of polyacrylate-based membranes has been examined. Application of differential system consisting of two H+-selective electrodes differing in the composition of internal electrolyte (with and without pH-buffer system) allowed to find that CO2 is able to permeate hexanediol diacrylate (HDDA)/isodecyl acrylate (IDA)/acrylonitrile (ACN) membrane. The second goal of this work was to confirm that hydrophobic properties of applied SAMs based on ferrocene-terminated thiols mixed with n-hexanethiol is mainly responsible for the prevention of aqueous layer formation between the ion-selective membrane and the surface of inner electrode. For this purpose two types of “aqueous layer” tests, based on transmembrane ion fluxes as well as CO2 diffusion, were carried out.