| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Clerck, Karen De
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (36/36 displayed)
- 2025Comparison of distinctive polymeric membrane structures as support materials for membrane extraction of chiral aminescitations
- 2024Low-Velocity Impact Resistance and Compression After Impact Strength of Thermoplastic Nanofiber Toughened Carbon/Epoxy Composites with Different Layupscitations
- 2024Low-Velocity Impact Resistance and Compression After Impact Strength of Thermoplastic Nanofiber Toughened Carbon/Epoxy Composites with Different Layupscitations
- 2022Continuous fiber-reinforced aramid/PETG 3D-printed composites with high fiber loading through fused filament fabricationcitations
- 2021Building the third dimension : microstructure and mechanics of Additive Manufactured continuous Aramid fiber/PETG composites with variable fiber content through in-nozzle impregnation
- 2021Toughening mechanisms responsible for excellent crack resistance in thermoplastic nanofiber reinforced epoxies through in-situ optical and scanning electron microscopycitations
- 2021Fully integrated flexible dielectric monitoring sensor system for real-time in situ prediction of the degree of cure and glass transition temperature of an epoxy resincitations
- 2021Long-term stiffness prediction of particle filled polymers by dynamic mechanical analysis : frequency sweep versus creep methodcitations
- 2021Lifting the quality of fused filament fabrication of polylactic acid based compositescitations
- 2020Nanofibre toughening of dissimilar interfaces in compositescitations
- 2020The transferability and design of commercial printer settings in PLA/PBAT fused filament fabricationcitations
- 2020Influencing parameters on measurement accuracy in dynamic mechanical analysis of thermoplastic polymers and their compositescitations
- 2020Immiscibility of chemically alike amorphous polymers : phase separation of poly(2-ethyl-2-oxazoline) and poly(2‑n‑propyl-2- oxazoline)citations
- 2020Delamination resistant composites by interleaving bio-based long-chain polyamide nanofibers through optimal control of fiber diameter and fiber morphologycitations
- 2020Effect of interleaved polymer nanofibers on the properties of glass and carbon fiber compositescitations
- 2019Composite Materials: Excellent nanofiber adhesion for hybrid polymer materials with high toughness based on matrix interdiffusion during chemical conversion (Adv. Funct. Mater. 8/2019)citations
- 2019Interdiffusing core-shell nanofiber interleaved composites for excellent Mode I and Mode II delamination resistancecitations
- 2019Bio-material polylactic acid/poly(butylene adipate-co-terephthalate) blend developed for extrusion- based additive manufacturing
- 2019Improving mechanical properties for extrusion-based additive manufacturing of poly(lactic acid) by annealing and blending with poly(3-hydroxybutyrate)citations
- 2019Bio-material polylactic acid/poly(butylene adipate-co-terephthalate) blend development for extrusion-based additive manufacturing
- 2017Electrospun nanofibers for highly toughened fibre reinforced polymer composite laminates
- 2017Improved fatigue delamination behaviour of composite laminates with electrospun thermoplastic nanofibrous interleaves using the Central Cut-Ply methodcitations
- 2016Damage-resistant composites using electrospun nanofibers: a multiscale analysis of the toughening mechanismscitations
- 2016TOWARDS DAMAGE RESISTANT COMPOSITES USING ELECTROSPUN NANOFIBERS: A MULTISCALE ANALYSIS OF THE TOUGHENING MECHANISMS
- 2016Electrospinning of sacrificial nanofibers for the creation of a self-healing nanovascular network and its effect on the properties of an epoxy matrix
- 2016Interlaminar toughening of resin transfer molded laminates by electrospun polycaprolactone structures : effect of the interleave morphologycitations
- 2016Blend electrospinning of dye-functionalized chitosan and polycaprolactoe : towards biocompatible pH-sensors
- 2016Increasing the damage resistance of composites by interleaving them with electrospun nanofibrous veils
- 2015Using a polyester binder for the interlaminar toughening of glass/epoxy composite laminates
- 2013Electrospinning of nanofibers for functional textile applications
- 2013Modifying the crack growth in a glass fiber reinforced epoxy by adding polyamide 6 nanofibers
- 2012Blend electrospinning of chitosan/polycaprolactone nanofibres
- 2012The influence of polyamide 6 nanofibres on the mechanical properties of glass fibre/epoxy composites
- 2012The pH-sensitive properties of azo dyes in aqueous environment
- 2011Morphology study of polyamide 6.9 nanofibres electrospun under steady state conditions
- 2006Development of electroconductive polyacrylonitrile fibers through chemical metallization and galvanisationcitations
Places of action
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article
Comparison of distinctive polymeric membrane structures as support materials for membrane extraction of chiral amines
Abstract
This study investigates the synthesis and performance of polymeric membranes for their potential application in supported liquid membranes (SLM), using the extraction of -methylbenzylamine (MBA), 1-methyl-3-phenylpropylamine (MPPA), and isopropyl amine (IPA) as a reference. Three synthesis methods — phase inversion, electrospinning, and stretching — were evaluated, each impacting the membrane morphology differently. The polymer selection influenced porosity, wettability, and surface free energy with PTFE exhibiting the highest hydrophobicity. Membrane wettability was assessed using the ionic liquid [P6,6,6,14][N(Tf)2] as the selective extractant, revealing that larger pore sizes enhanced the impregnation efficiency, while reducing the final SLM stability. Solute fluxes and selectivity were quantified; electrospun membranes exhibited higher fluxes, ranging from 1.0 to 1.2 g/(m2h) for MBA, 2.1 to 2.2 g/(m2h) for MPPA, and 0.8 to 1.2 g/(m2h) for IPA, along with a higher selectivity compared to phase inversion membranes, with fluxes ranging from 0.2 to 0.3 g/(m2h) for MBA, 0.2 g/(m2h) for MPPA, and 0.3 to 0.4 g/(m2h) for IPA. Stretched membranes demonstrated a comparable selectivity (MBA/IPA = 2.2, MPPA/IPA = 3.9), but reduced fluxes with increasing pore size, decreasing from 2.7 to 0.5 g/(m2h) for MBA, 4.9 to 0.9 g/(m2h) for MPPA, and 1.2 to 0.3 g/(m2h) for IPA, as the nominal pore size increased from 50 to 450 nm. This phenomenon likely resulted from the improved impregnation efficiency, coupled with a lower porosity and larger thickness in the membranes with larger pores. Overall, the membrane morphology significantly influenced the SLM performance and stability, with homogeneous, porous membranes possessing smaller pore sizes and high hydrophobicity exhibiting optimal characteristics. These findings underscore the critical role of membrane structure and properties in SLM applications.