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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tammelin, Tekla
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Interfacial Engineering of Soft Matter Substrates by Solid-State Polymer Adsorption
- 2024Advanced nanocellulose-based electrochemical sensor for tetracycline monitoringcitations
- 2023Protein Adsorption and Its Effects on Electroanalytical Performance of Nanocellulose/Carbon Nanotube Composite Electrodescitations
- 2022Pilot-scale modification of polyethersulfone membrane with a size and charge selective nanocellulose layercitations
- 2022Pilot-scale modification of polyethersulfone membrane with a size and charge selective nanocellulose layercitations
- 2021Functionalized Nanocellulose/Multiwalled Carbon Nanotube Composites for Electrochemical Applicationscitations
- 2020Upcycling Poultry Feathers with (Nano)cellulose:Sustainable Composites Derived from Nonwoven Whole Feather Preformscitations
- 2019Cationic starch as strengthening agent in nanofibrillated and bacterial cellulose nanopapers
- 2018Structural distinction due to deposition method in ultrathin films of cellulose nanofibrescitations
- 2018Foam-formed fibre materials
- 2018Effect of cellulosic fibers on foam dynamics
- 2017Strongly reduced thermal conductivity in hybrid ZnO/nanocellulose thin filmscitations
- 2017Sample geometry dependency on the measured tensile properties of cellulose nanopaperscitations
- 2017In situ TEMPO surface functionalization of nanocellulose membranes for enhanced adsorption of metal ions from aqueous mediumcitations
- 2015Phase behaviour and stability of nanocellulose stabilized oil-in-water emulsions
- 2015Correlation between cellulose thin film supramolecular structures and interactions with watercitations
- 2014Nanofibrillated cellulose, poly(vinyl alcohol), montmorillonite clay hybrid nanocomposites with superior barrier and thermomechanical propertiescitations
- 2012Nano-fibrillated cellulose vs bacterial cellulose
- 2012High performance cellulose nanocompositescitations
- 2012High performance cellulose nanocomposites:Comparing the reinforcing ability of bacterial cellulose and nanofibrillated cellulosecitations
- 2012Nano-fibrillated cellulose vs bacterial cellulose:Reinforcing ability of nanocellulose obtained topdown or bottom-up
- 2011Quantitative assessment of the enzymatic degradation of amorphous cellulose by using a quartz crystal microbalance with dissipation monitoringcitations
- 2011Nanocomposite packaging materials from polysaccharides and montmorillonite
- 2010Multifunctional barrier films and coatings from biopolymers via enzymatic modification
- 2010Bio-hybrid nanocomposite coatings from polysaccharides and nanoclay
- 2003Adsorption of cationic starch on anionic silica studied by QCM-D ; Kationisen tärkkelyksen adsorptio anioniselle SiO2-pinnalle
Places of action
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article
Pilot-scale modification of polyethersulfone membrane with a size and charge selective nanocellulose layer
Abstract
<p>The utilisation of plant-derived nanoscale cellulosic materials (cellulose nanofibrils, CNF) in tailoring water purification membranes is constantly gaining interest in the context of green-functionalised membrane solutions. However, most of the existing approaches based on renewable and biobased materials suffer from the lack of efficient and scalable processing strategies. Here, we introduce a roll-to-roll membrane modification approach based on thin submicron nanocellulose coatings (400-800 nm) to manufacture anti-biofouling membranes with size and charge dependent selectivity using unit operations compatible with existing industrial lines. We turned a commercial polymeric polyethersulfone (PES) microfiltration membrane into highly hydrophilic and tight membrane structure by applying thin and water-durable cellulose nanofibril layers using cast or spray coating methods. Nanocellulose coated membranes exhibited water permeance values of 80 - 100 LMH/MPa with the highest rejection levels of > 90% for Cytochrome C. Furthermore, the nanocellulose layers were able to withstand relatively high filtration pressure levels of 1 MPa, indicating that the selected procedures to improve mechanical integrity i.e. polyethylene imine-based anchoring and acid induced CNF cross-linking were successful. The coated membranes with the thinnest nanocellulose layer exhibited a molecular weight cut-off (MWCO) of 2 kDa for negatively charged polystyrene sulfonate and 14 kDa for neutral dextrane indicating charge selective behaviour. It can be concluded that our nanocellulose coated PES membranes represent nanofiltration membranes and lower boundary of ultrafiltration membranes with clear anti-biofouling performance directly evidenced via systematic bovine serum albumin (BSA) adsorption investigations. Our approach paves the way towards tunable and sustainable water treatment technologies simultaneously opening space for novel biobased solutions in membrane sector.</p>