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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tauanov, Z.
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Topics
Publications (4/4 displayed)
- 2020Mercury reduction and chemisorption on the surface of synthetic zeolite silver nanocompositescitations
- 2019Synthetic sodalite doped with silver nanoparticlescitations
- 2019Removal of iodide from water using silver nanoparticles-impregnated synthetic zeolitescitations
- 2018Synthetic coal fly ash-derived zeolites doped with silver nanoparticles for mercury (II) removal from watercitations
Places of action
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article
Removal of iodide from water using silver nanoparticles-impregnated synthetic zeolites
Abstract
<p>Synthetic zeolite-based Ag-nanocomposites were synthesized, characterized and used to remove iodide from aqueous solutions. The results showed high removal efficiency (up to 94.85%)and the formation silver iodide which is stable into the material. The maximum achieved adsorption capacity of the nanocomposites was between 19.54 and 20.44 mg/g. The removal mechanism was meticulously studied by taking into account both water chemistry and surface interactions backed by multiple characterization techniques, such as XRD, XRF, SEM/EDX, TEM and BET. The qualitative and quantitative examination of pre- and post-adsorption of nanocomposite samples proved that the anchored silver iodide was formed via oxidation of initial silver nanoparticles followed by reaction with iodide to form a stable crystalline precipitate on the surface of the materials. A diffusion-based adsorption model indicated that the controlling mechanism is a slow intraparticle surface diffusion with diffusion coefficients in the range of 0.37–1.72 × 10<sup>−13</sup> cm<sup>2</sup>/s. The investigation of competing and co-existing anions (Cl<sup>−</sup>, Br<sup>−</sup>, CO<sub>3</sub> <sup>2−</sup>, and CrO<sub>4</sub> <sup>2−</sup>)on the removal efficiency of iodide demonstrated a negligible effect showing a kinetically favorable precipitation reaction of iodide over other anions.</p>