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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cundy, Andy
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2020Novel nanostructured iron oxide cryogels for arsenic (As(III)) removalcitations
- 2019A cryogel-based bioreactor for water treatment applicationscitations
- 2019Flexural performance of reinforced concrete beams strengthened with fibre reinforced geopolymer concrete under accelerated corrosioncitations
- 2018A novel corrosion resistant repair technique for existing reinforced concrete (RC) elements using polyvinyl alcohol fibre reinforced geopolymer concrete (PVAFRGC)citations
- 2017Steel fibre reinforced geopolymer concrete (SFRGC) with improved microstructure and enhanced fibre-matrix interfacial propertiescitations
- 2017Tensile properties of a novel fibre reinforced geopolymer composite with enhanced strain hardening characteristicscitations
- 2017Effect of undensified silica fume on the dispersion of carbon nanotubes within a cementitious compositecitations
- 2017Mechanical performance of novel cement-based composites prepared with nano-fibres, and hybrid nano- and micro-fibrescitations
- 2016Development of geopolymer mortar under ambient temperature for in situ applicationscitations
- 2014y-Al2O3-based nanocomposite adsorbents for arsenic(V) removal: Assessing performance, toxicity and particle leakagecitations
- 2012Driving forces of conformational changes in single-layer graphene oxidecitations
- 2011High efficiency removal of dissolved As(III) using iron nanoparticle-embedded macroporous polymer compositescitations
- 2005Electrokinetic iron pan generation in unconsolidated sediments: implications for contaminated land remediation and soil engineeringcitations
Places of action
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article
y-Al2O3-based nanocomposite adsorbents for arsenic(V) removal: Assessing performance, toxicity and particle leakage
Abstract
The generation and development of effective adsorption materials for arsenic removal are urgently needed due to acute arsenic contamination of water sources in many regions around the world. In the search for these new adsorbents, the application of nanomaterials or nanocomposites, and especially the use of nanoparticles (NPs), has proven increasingly attractive. While the adsorptive performance of a range of nanocomposite and nanomaterial-based systems has been extensively reviewed in previously-published literature, the stability of these systems in terms of NP release, i.e. the ability of the nanomaterial or nanocomposite to retain incorporated NPs, is less well understood. Here we examine the performance of nanocomposites comprised of aluminium oxide nanoparticles (AluNPs) incorporated in macroporous polyacrylamide-based cryogels (n-Alu-cryo, where n indicates the percentage of AluNPs in the polymer material (n = 0–6%, w/v)) for As(V) adsorption, and evaluate AluNP leakage before and after the use of these materials. A range of techniques is utilised and assessed (SEM, TEM, mass weight change, PIXE and in vitro toxicity studies). The 4-Alu-cryo nanocomposite was shown to be optimal for minimising AluNP losses while maximising As(V) removal. From the same nanocomposite we were further able to show that NP losses were not detectable at the AluNP concentrations used in the study. Toxicity tests revealed that no cytotoxic effects could be observed. The cryogel-AluNPs composites were not only effective in As(V) removal but also in immobilising the AluNPs. More challenging flow-through conditions for the evaluation of NP leakage could be included as a next step in a continued study assessing particle loss and subsequent toxicity.