• Villaro Ábalos, Elvira
• Karagiannidis, Panagiotis
• Gómez, Julio
• Elmarakbi, Ahmed

Abstract

n this work, different graphene-related materials (GRMs) and polyamide-6 (PA6) were melt compounded by twin screw extrusion. The GRMs prepared were graphene nanoplatelets (GNPs), graphene oxide (GO), reduced graphene oxide (rGO) and silane functionalised reduced graphene oxide (f-rGO). The GRMs had comparable lateral size (20–30 ​μm), but different thickness and surface chemistry which resulted in different behaviour in processing of melt flow, maximum loading in the PA6 matrix (15%wt for GNPs, 10%wt for GO, 2%wt for rGO and 2.5%wt for f-rGO) as well as mechanical properties. A second extrusion phase produced formulations with lower concentration of GRMs. In the case of f-rGO/PA6, the melt flow index increased by over 76% at 0.5%wt loading compared with the pure PA6 resin, facilitating processing and dispersion of the flakes within the matrix and increasing the Young´s modulus (E) and tensile strength by 39%. However, high filler content above 10% has been achieved only for GNPs improving the Young´s modulus by 50% at 15%wt.

Topics

• nanocomposite
• morphology
• dispersion
• surface
• melt
• extrusion
• twin screw extrusion
• strength
• tensile strength
• resin