| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Van Hecke, Kristof
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Elucidating the Non-Covalent Interactions that Trigger Interdigitation in Lead-Halide Layered Hybrid Perovskites.citations
- 2024Elucidating the non-covalent interactions that trigger interdigitation in lead-halide layered hybrid perovskitescitations
- 2024Analysis of COF-300 synthesis: probing degradation processes and 3D electron diffraction structure
- 2023Visible light‐fueled mechanical motions with dynamic phosphorescence induced by topochemical [2+2] reactions in organoboron crystalscitations
- 20233D Perovskite Passivation with a Benzotriazole-Based 2D Interlayer for High-Efficiency Solar Cells.
- 20233D perovskite passivation with a benzotriazole-based 2D interlayer for high-efficiency solar cellscitations
- 2023Turning 3D covalent organic frameworks into luminescent ratiometric temperature sensorscitations
- 2022Improving green Yb3+/Er3+ upconversion luminescence by co-doping metal ions into an oxyfluoride matrix
- 2022Hybrid lanthanide-doped rattle-type thermometers for theranosticscitations
- 2022CuI nanoparticle-catalyzed regioselective synthesis of 3-nitro-2-arylimidazo[1,2-a]pyridines using oxygen as oxidantcitations
- 2021Directing the self-assembly of conjugated organic ammonium cations in low-dimensional perovskites by halide substitutioncitations
- 2019Chromium(iii) in deep eutectic solvents: towards a sustainable chromium(vi)-free steel plating processcitations
- 2018Ring opening copolymerisation of lactide and mandelide for the development of environmentally degradable polyesters with controllable glass transition temperaturescitations
- 2018Understanding the importance of Cu(I) intermediates in self-reducing molecular inks for flexible electronicscitations
- 2016Mechanochemically synthesized crystalline luminescent 2D coordination polymers of La3+ and Ce3+, doped with Sm3+, Eu3+, Tb3+, and Dy3+: synthesis, crystal structures and luminescencecitations
- 2012Crystal structures of low-melting ionic transition-metal complexes with N-alkylimidazole ligandscitations
- 2010Cobalt(II) complexes of nitrile-functionalized ionic liquidscitations
- 2009Pyrrolidinium Ionic Liquid Crystalscitations
- 2004Lanthanide(III) nitrobenzenesulfonates as new nitration catalysts: The role of the metal and of the counterion in the catalytic efficiencycitations
Places of action
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article
Ring opening copolymerisation of lactide and mandelide for the development of environmentally degradable polyesters with controllable glass transition temperatures
Abstract
Environmentally degradable polyesters offer an interesting perspective for a vast number of applications. However, current front-runners like poly(lactide), poly(glycolide) and poly(e-caprolactone) are either semi crystalline excluding applications for which optical transparency is desired, or exhibit low glass transition temperatures (T-s) resulting in poor dimensional stability at temperatures exceeding the T-g. In the present work, copolymers of lactide and mandelide are explored as a method to obtain amorphous, environmentally degradable polyesters with a glass transition temperature exceeding 50 degrees C. Mandelide and lactide can be successfully copolymerised and the resulting copolymers revealed rising T-g values upon increasing the mandelide content. The obtained molecular weights were superior to the molecular weights previously obtained via poly condensation, but were limited by the epimerisation of the mandelide monomer, which passes through an enolic intermediate that is able to initiate the polymerisation.