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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kontturi, Eero
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2025Mechanoenzymatic hydrolysis of cotton to cellulose nanocrystals
- 2024Interfacial Engineering of Soft Matter Substrates by Solid-State Polymer Adsorption
- 2024Assessment of the Alga Cladophora glomerata as a Source for Cellulose Nanocrystalscitations
- 2024Wood flour and Kraft lignin enable air-drying of the nanocellulose-based 3D-printed structurescitations
- 2023Thermodynamically controlled multiphase separation of heterogeneous liquid crystal colloidscitations
- 2023Thermodynamically controlled multiphase separation of heterogeneous liquid crystal colloidscitations
- 2022Effect of Moisture on Polymer Deconstruction in HCl Gas Hydrolysis of Woodcitations
- 2022Solid-state polymer adsorption for surface modification: The role of molecular weightcitations
- 2021Visualizing Degradation of Cellulose Nanofibers by Acid Hydrolysiscitations
- 2021Visualizing Degradation of Cellulose Nanofibers by Acid Hydrolysiscitations
- 2021From micro to nano : polypropylene composites reinforced with TEMPO-oxidised cellulose of different fibre widthscitations
- 2021Grow it yourself composites: delignification and hybridisation of lignocellulosic material using animals and fungicitations
- 2020Nanomaterials Derived from Fungal Sources-Is It the New Hype?citations
- 2020Plastic to elastic: Fungi-derived composite nanopapers with tunable tensile propertiescitations
- 2020Plastic to elastic : Fungi-derived composite nanopapers with tunable tensile propertiescitations
- 2019Cellulose carbamate derived cellulose thin films: preparation, characterization and blending with cellulose xanthatecitations
- 2019Sustainable High Yield Route to Cellulose Nanocrystals from Bacterial Cellulosecitations
- 2019Sustainable High Yield Route to Cellulose Nanocrystals from Bacterial Cellulosecitations
- 2019Nanomaterials Derived from Fungal Sources - Is It the New Hype?citations
- 2018Structural distinction due to deposition method in ultrathin films of cellulose nanofibrescitations
- 2018Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranescitations
- 2017Strongly reduced thermal conductivity in hybrid ZnO/nanocellulose thin filmscitations
- 2016Parameters affecting monolayer organisation of substituted polysaccharides on solid substrates upon Langmuir-Schaefer depositioncitations
- 2015Chemical characteristics of squeezable sap of hydrothermally treated silver birch logs (Betula pendula)citations
- 2015The Effect of Hydrothermal Treatment on the Color Stability and Chemical Properties of Birch Veneer Surfacescitations
- 2015Chemical characteristics of squeezable sap of hydrothermally treated silver birch logs (Betula pendula):Effect of treatment time and the quality of the soaking water in pilot scale experimentcitations
- 2011Polyelectrolyte Brushes Grafted from Cellulose Nanocrystals Using Cu-Mediated Surface-Initiated Controlled Radical Polymerization.citations
- 2011The effect of hydrothermal pre-treatment on the chemical characteristics of the xylem of silver birch
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article
Parameters affecting monolayer organisation of substituted polysaccharides on solid substrates upon Langmuir-Schaefer deposition
Abstract
Cellulose esters with varying ester and residual hydroxyl group contents represent a cheap and pliable bio-based polysaccharide to examine. In this work, the molecular organization of cellulose triacetate, cellulose acetate propionate and cellulose acetate butyrate as a response to a variety of external parameters are investigated. The morphology of ultrathin films of the cellulose esters, transferred by means of Langmuir-Schaefer (LS) deposition from the air/water interface to the surface of solid substrates, are shown to be induced by the total surface free energy of each substrate. Additionally, the spreading capability of the esters is investigated - the spread of each polymer is directly linked to its chemical composition, namely the proportion of unsubstituted hydroxyl groups remaining on the glucose backbone. Monomer arrangement at the air/water interface has a distinct dependency on the rate at which their monolayers are compressed. The study provides a systematic approach to the investigations of LS deposition of cellulose esters.