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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mol, Johannes M. C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Biodegradation of Oxide Nanoparticles in Apoferritin Protein Media: A Systematic Electrochemical Approachcitations
- 2020Nanorods grown by copper anodizing in sodium carbonatecitations
- 2020Effect of simulated brazing on the microstructure and corrosion behavior of twin roll cast AA3003citations
- 2019An in situ spectro-electrochemical monitoring of aqueous effects on polymer/metal oxide interfacescitations
- 2018In situ methanol adsorption on aluminum oxide monitored by a combined ORP-EIS and ATR-FTIR Kretschmann setupcitations
- 2018Compositional study of a corrosion protective layer formed by leachable lithium salts in a coating defect on AA2024-T3 aluminium alloyscitations
- 2018Fluoride-Induced Interfacial Adhesion Loss of Nanoporous Anodic Aluminium Oxide Templates in Aerospace Structurescitations
- 2017Interface strength and degradation of adhesively bonded porous aluminum oxidescitations
- 2017Interface strength and degradation of adhesively bonded porous aluminum oxidescitations
- 2017Towards Cr(VI)-free anodization of aluminum alloys for aerospace adhesive bonding applicationscitations
- 2017In Situ Characterization of the Initial Effect of Water on Molecular Interactions at the Interface of Organic/Inorganic Hybrid Systemscitations
- 2017Unravelling the chemical influence of water on the PMMA/aluminum oxide hybrid interface in situcitations
Places of action
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article
Compositional study of a corrosion protective layer formed by leachable lithium salts in a coating defect on AA2024-T3 aluminium alloys
Abstract
Organic primer coatings loaded with environmentally harmful Cr(VI) corrosion inhibitive pigments still play an important role in corrosion protection of aluminium alloys for the aerospace industry. A potential “green” alternative coating system has recently been developed, loaded with lithium salt corrosion inhibitors. Under exposure to neutral salt spray, lithium salts leach from the organic coating into coating defects to induce the formation of a corrosion protective layer. In this work the composition and growth of this protective layer is investigated by time-of-flight secondary ion mass spectrometry (ToF-SIMS). ToF-SIMS imaging is successfully applied to monitor the lateral spread of leaching lithium salts in artificial 1-mm-wide scribes. The chemical composition of the protective layer is revealed by comparing the mass spectra of salt spray exposed scribe areas to the mass spectra of pseudoboehmite and aluminium-lithium layered double hydroxide reference samples. The insights obtained in this work have led to a thorough understanding of the formation mechanism of the protective layer and provide local chemical and structural information which can be linked to corrosion protection behavior. ; Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. ; OLD Virtual Materials and Mechanics ; (OLD) MSE-6 ; (OLD) MSE-1