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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Huang, Ying
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Topics
Publications (8/8 displayed)
- 2024Evaluation of Pigment-Modified Clear Binders and Asphalts: An Approach towards Sustainable, Heat Harvesting, and Non-Black Pavementscitations
- 2023(Keynote) Insight into Carbon Corrosion of Different Carbon Supports for Pt-Based Electrocatalysts for Polymer Electrolyte Fuel Cells from Interfacial Perspective
- 2023(Keynote) Insight into Carbon Corrosion of Different Carbon Supports for Pt-Based Electrocatalysts for Polymer Electrolyte Fuel Cells from Interfacial Perspective
- 2023Engineered living materials for the conversion of a low-cost food-grade precursor to a high-value flavonoid
- 2023Engineered living materials for the conversion of a low-cost food-grade precursor to a high-value flavonoidcitations
- 2023Engineered living materials for the conversion of a low-cost foodgrade precursor to a high-value flavonoidcitations
- 2021A new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactidecitations
- 2021Improved rheology, crystallization, and mechanical performance of PLA/mPCL blends prepared by electron-induced reactive processingcitations
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article
A new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactide
Abstract
Biodegradable polylactide/masticated natural rubber (PLA/mNR) blends were prepared by electron induced reactive processing (EIReP) without using any chemical additives. The PLA/mNR blends showed droplet-matrix morphology with decreased mNR particle size after EIReP treatment. The absolute value of complex viscosity and storage modulus increased significantly for the EIReP modified blends, suggesting the improved melt strength and elasticity. The crystallization investigation showed that the cold crystallization peak of PLA phase gradually disappeared after EIReP modification. Instead, the crystallization peak arose during melt cooling process. Consequently, the crystallinity of PLA phase increased from 6.2% to 39.0% as the mNR content increased from 0 to 20 wt%. It was found that the softening temperature of PLA examined by dynamic mechanical analysis increased effectively with the characters of higher modulus compared to the non-modified blends. The EIReP modified blends exhibited excellent mechanical properties with 7-fold increase of impact toughness compared with neat PLA, implying a superior interfacial adhesion and chain interactions between the two polymer phases. Furthermore, the thermogravimetric analysis demonstrated that the thermal stability was slightly enhanced for the EIReP modified blends. ; publishedVersion