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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Müller, Michael Thomas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Additive Free Crosslinking of Poly-3-hydroxybutyrate via Electron Beam Irradiation at Elevated Temperaturescitations
- 2023Effect of electron beam irradiation on thermal stability and crystallization behavior of flexible copolyester/multiwalled carbon nanotubes nanocompositescitations
- 2023Influence of temperature and dose rate of e‐beam modification on electron‐induced changes in polyacrylonitrile fiberscitations
- 2022Thermoelectric Performance of Polypropylene/Carbon Nanotube/Ionic Liquid Composites and Its Dependence on Electron Beam Irradiationcitations
- 2021A new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactidecitations
- 2020Laccase-Enzyme Treated Flax Fibre for Use in Natural Fibre Epoxy Compositescitations
- 2019Influence of a supplemental filler in twin-screw extruded PP/CNT composites using masterbatch dilutioncitations
- 2019In-Line Nanostructuring of Glass Fibres Using Different Carbon Allotropes for Structural Health Monitoring Applicationcitations
- 2018Online Structural-Health Monitoring of Glass Fiber-Reinforced Thermoplastics Using Different Carbon Allotropes in the Interphase
- 2018Enhanced Interfacial Shear Strength and Critical Energy Release Rate in Single Glass Fiber-Crosslinked Polypropylene Model Microcompositescitations
- 2017Effect of Graphite Nanoplate Morphology on the Dispersion and Physical Properties of Polycarbonate Based Compositescitations
- 2016Electrical Conductive Surface Functionalization of Polycarbonate Parts with CNT Composite Films during Injection Moldingcitations
- 2013Influence of talc with different particle sizes in melt-mixed LLDPE/MWCNT compositescitations
- 2012A successful approach to disperse MWCNTs in polyethylene by melt mixing using polyethylene glycol as additivecitations
- 2011Influence of feeding conditions in twin-screw extrusion of PP/MWCNT composites on electrical and mechanical propertiescitations
Places of action
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article
A new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactide
Abstract
Biodegradable polylactide/masticated natural rubber (PLA/mNR) blends were prepared by electron induced reactive processing (EIReP) without using any chemical additives. The PLA/mNR blends showed droplet-matrix morphology with decreased mNR particle size after EIReP treatment. The absolute value of complex viscosity and storage modulus increased significantly for the EIReP modified blends, suggesting the improved melt strength and elasticity. The crystallization investigation showed that the cold crystallization peak of PLA phase gradually disappeared after EIReP modification. Instead, the crystallization peak arose during melt cooling process. Consequently, the crystallinity of PLA phase increased from 6.2% to 39.0% as the mNR content increased from 0 to 20 wt%. It was found that the softening temperature of PLA examined by dynamic mechanical analysis increased effectively with the characters of higher modulus compared to the non-modified blends. The EIReP modified blends exhibited excellent mechanical properties with 7-fold increase of impact toughness compared with neat PLA, implying a superior interfacial adhesion and chain interactions between the two polymer phases. Furthermore, the thermogravimetric analysis demonstrated that the thermal stability was slightly enhanced for the EIReP modified blends. ; publishedVersion