| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Jakobsen, Bo
Roskilde University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024RUSC (Roskilde University Shear Code)
- 2023Solvothermal vapor annealing setup for thin film treatment:A compact design with in situ solvent vapor concentration probecitations
- 2023Solvothermal vapor annealing setup for thin film treatmentcitations
- 2023Thin film and bulk morphology of PI-PS-PMMA miktoarm star terpolymers with both weakly and strongly segregated arm pairs
- 2022Piezoelectric shear rheometrycitations
- 2018High-pressure cell for simultaneous dielectric and neutron spectroscopycitations
- 2015Communication: High pressure specific heat spectroscopy reveals simple relaxation behavior of glass forming molecular liquidcitations
- 2014High-Resolution Reciprocal Space Mapping for Characterizing Deformation Structurescitations
- 2007Investigation of the deformation structure in an aluminium magnesium alloy by high angular resolution three-dimensional X-ray diffractioncitations
- 2007Direct determination of elastic strains and dislocation densities in individual subgrains in deformation structurescitations
- 2006In-situ studies of bulk deformation structures: Static properties under load and dynamics during deformation
- 2005Dielectric and shear mechanical relaxations in glass-forming liquidscitations
Places of action
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article
Thin film and bulk morphology of PI-PS-PMMA miktoarm star terpolymers with both weakly and strongly segregated arm pairs
Abstract
<p>A series of three homologous ABC miktoarm star terpolymers having a polyisoprene (PI), a polystyrene (PS) and a poly(methyl methacrylate) (PMMA) arm, is synthesized by living anionic polymerization. While the volume fraction of the PI and the PS blocks are kept equal and constant, the volume fraction of the PMMA block is varied. The room temperature bulk structure is characterized using small-angle X-ray scattering and transmission electron microscopy, while the structure of thin films is investigated using scanning electron microscopy, atomic force microscopy and X-ray reflectometry. For both bulk and thin films, it is found that the sample with the lowest volume fraction of PMMA has a morphology distinctly different from the two samples with larger PMMA volume fraction. All data for both bulk and thin film samples are consistent with an alternating lamellar structure for the lowest PMMA volume fraction sample. The two higher PMMA volume fraction samples show standing rod structure, however the details of the packing in the PMMA matrix differ depending on sample thickness. Overall, a structure with PI domains screened from interacting with PMMA by a PS shell is seen for both samples. In bulk, core-shell cylinders pack hexagonally, while a 100 nm thin film of the sample with the largest volume fraction of PMMA shows a square-lattice packing. The structuring is driven by two factors: i) the strong segregation of the PI-PMMA arm pair together with the weak segregation of the two arm pairs with a PS block and ii) the geometrical constraints resulting from the star architecture. No wetting layers are observed for any of the thin film samples, neither at the air-polymner surface or at the polymer-substrate interface.</p>