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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Combeaud, Christelle
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Topics
Publications (11/11 displayed)
- 2024Influence of the use of mechanically recycled pet in injection stretch blow moulding process (ISBM)
- 2023A Comparative Study on Crystallisation for Virgin and Recycled Polyethylene Terephthalate (PET): Multiscale Effects on Physico-Mechanical Propertiescitations
- 2021Effects of annealing prior to stretching on strain induced crystallization of polyethylene terephthalatecitations
- 2020Strain-induced crystallization of poly(ethylene 2,5-furandicarboxylate). Mechanical and crystallographic analysiscitations
- 2018Strain induced crystallization in biobased Poly(ethylene 2,5-furandicarboxylate) (PEF); conditions for appearance and microstructure analysiscitations
- 2017Structure and properties of polypropylene/graphene nanoplatelets microcomposites: effect of graphene size.
- 2015Thermo-mechanical behavior in Poly(methyl methacrylate) with different molecular weights.
- 2015Thermo-mechanical behavior in Poly(methyl methacrylate) with different molecular weights.
- 2015An Analysis of Transcrystallinity in Polymers
- 2010Biaxial tension on polymer in thermoforming rangecitations
- 2006Polymer processing extrusion instabilities and methods for their elimination or minimisation
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article
Strain induced crystallization in biobased Poly(ethylene 2,5-furandicarboxylate) (PEF); conditions for appearance and microstructure analysis
Abstract
Poly(ethylene 2,5-furandicarboxylate) (PEF) is an emerging biobased thermoplastic polymer that may replace PET for stretching applications such as bottle blowing, thermoforming, or film extrusion. The stretch ability and strain induced microstructure in PEF have not been fully addressed in the literature despite being the key issue for industrial processing. In this study, it is demonstrated that PEF can develop an organized crystalline-like microstructure under uni-axial stretching above its glass transition and can exhibit behavior close to that of PET with drastic strain hardening and coupled sensitivities to strain rate and temperature. The time-temperature superposition principle appeared to make it possible to map stretch ability in terms of strain rate and temperature , and to develop conditions for strain-induced crystallization (SIC). The periodic microstructure of stretched PEF was highlighted by means of wide-angle X-Ray scattering and analyzed with stochastically modulated temperature DSC (TOPEM). Depending on the stretching conditions applied to PEF, different morphologies of crystals are developed. The heat capacity (ΔC P), crystalline fraction (X C), mobile amorphous fraction (X MAF), and rigid amorphous fraction (X RAF) for stretched and non-stretched PEF samples were evaluated .