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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jena, Rajeeb Kumar
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2018Development of a 3D graphene aerogel and 3D porous graphene/MnO 2 @polyaniline hybrid film for all-solid-state flexible asymmetric supercapacitorscitations
- 2017Development of 3D Urchin-Shaped Coaxial Manganese Dioxide@Polyaniline (MnO2@PANI) Composite and Self-Assembled 3D Pillared Graphene Foam for Asymmetric All-Solid-State Flexible Supercapacitor Applicationcitations
- 2015Non-covalent interactions and supercapacitance of pseudo-capacitive composite electrode materials (MWCNT-COOH/MnO2/PANI)citations
- 2015Graphene/heparin template-controlled polyaniline nanofibers composite for high energy density supercapacitor electrodecitations
- 2014Synthesis of graphene/vitamin C template-controlled polyaniline nanotubes composite for high performance supercapacitor electrodecitations
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article
Synthesis of graphene/vitamin C template-controlled polyaniline nanotubes composite for high performance supercapacitor electrode
Abstract
A graphene nanosheet/polyaniline nanotube (GPNT) composite is prepared for the first time by in-situ chemical oxidative polymerization of aniline using vitamin C as a structure directing agent. The vitamin C molecules lead to the synthesis of polyaniline (PANI) nanotubes through the development of rod-like assembly by H-bonding in an aqueous medium. The initially synthesized graphene oxide/polyaniline nanotubes composite is reduced to graphene using hydrazine monohydrate followed by re-oxidation and protonation of the PANI to produce the GPNT nanocomposite. This novel composite showed a high specific capacitance of 534.37 F/g and an excellent energy density of 74.27 Wh/kg at a constant current of 0.5 mA. Besides, the GPNT composite exhibited excellent cycle life with 91.4% specific capacitance retained after 500 charge-discharge cycles. The excellent performance is due to the synergistic combination of graphene which provides good electrical conductivity and mechanical stability, and PANI nanofiber which deals with good redox activity. © 2014 Published by Elsevier Ltd.