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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Barg, Suelen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2022Joule heating and mechanical properties of epoxy/graphene based aerogel compositecitations
- 2022Tailoring the microstructure of lamellar Ti3C2Tx MXene aerogel by compressive strainingcitations
- 2021Realization of 3D epoxy resin/Ti3C2Tx MXene aerogel composites for low-voltage electrothermal heatingcitations
- 2021Unused to useful: Recycling plasma chamber coated waste composite of ZnO and α-Fe2O3 into an active material for sustainable waste-water treatment
- 2020MXene-Based 3D Porous Macrostructures for Electrochemical Energy Storagecitations
- 2020Direct 3D Printing of Graphene Using Capillary Suspensionscitations
- 2020Heteroatom‐Doped and Oxygen‐Functionalized Nanocarbons for High‐Performance Supercapacitorscitations
- 2016Light and Strong SiC Networkscitations
- 2016Light and Strong SiC Networkscitations
- 2015Printing in Three Dimensions with Graphenecitations
- 2014Macroporous polymer nanocomposites synthesised from high internal phase emulsion templates stabilised by reduced graphene oxidecitations
- 2010Producing open-porous inorganic component with layer having homogenous pore structure, comprises solidifying emulsion consisting of stabilized aqueous inorganic suspension, alkane and emulsifier to obtain basic body by freezing process
- 2009New cellular ceramics from high alkane phase emulsified suspensions (HAPES)citations
- 2009New cellular ceramics from high alkane phase emulsified suspensions (HAPES)citations
- 2009Processing and Properties of Graded Ceramic Filterscitations
- 2008Modeling of glass sintering applied for the fabrication of porous glass bodiescitations
- 2008Cellular ceramics by direct foaming of emulsified ceramic powder suspensionscitations
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article
Macroporous polymer nanocomposites synthesised from high internal phase emulsion templates stabilised by reduced graphene oxide
Abstract
Reduced graphene oxide (rGO) is known to be electrically conductive and adsorb at oil water interfaces. It has also been shown to mechanically reinforce bulk materials. This work combines these favourable characteristics of two-dimensional rGO to develop 3D macroporous polymer nanocomposites via emulsion templating. rGO proved to be an efficient emulsifier as only 0.2 mg/ml (with respect to the oil phase) of rGO was required to stabilise water-in-oil high internal phase emulsions (HIPE) of up to 80 vol.% internal phase. After polymerisation of the continuous minority monomer (styrene and divinylbenzene) phase, macroporous polymer nanocomposites with tuneable microstructures were obtained. The storage modulus of rGO-poly(styrene-co-divinylbenzene) HIPEs increased by almost an order of magnitude when the rGO concentration used to stabilise the HIPE template increased from 0.4 to 5.0 mg/ml. The adsorption and organisation of rGO at the o/w interface in HIPEs prior to polymerisation and partial aggregation in the polymer cell walls after polymerisation resulted in conductive nanocomposites with a rGO content of as low as 0.006 vol.% (with respect to bulk polymer volume or 0.8 mg/ml with respect to the monomer volume used in the emulsion template) compared to 0.1 vol.% for dense nanocomposites previously reported. This provided evidence for the efficient arrangement of rGO within the macroporous polymer nanocomposite, creating an electrically conductive network. (C) 2013 Elsevier Ltd. All rights reserved.