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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zakri, Cécile
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2023High‐Energy‐Density Waterborne Dielectrics from Polyelectrolyte‐Colloid Complexescitations
- 2019Shape memory nanocomposite fibers for untethered high-energy microengines.citations
- 2018Preparation and electrical conductivity of different fibres prepared from vertically aligned carbon nanotubes
- 2018Giant Electrostriction of Soft Nanocomposites Based on Liquid Crystalline Graphenecitations
- 2017Large scale conductive films and patterns based on carbon nanotubes and graphene liquid crystals
- 2017Giant Electrostrictive Response and Piezoresistivity of Emulsion Templated Nanocompositescitations
- 2015Graphene liquid crystal retarded percolation for new high-k materialscitations
- 2015Graphene liquid crystal retarded percolation for new high-k materialscitations
- 2015Giant Permittivity Polymer Nanocomposites Obtained by Curing a Direct Emulsioncitations
- 2013Changes of morphology and properties of block copolymers induced by carbon nanotubescitations
- 2012Conductivity and percolation of nanotube based polymer composites in extensional deformationscitations
- 2011Scalable Process for the Spinning of PDV-CArbon Nanotube composite Fiberscitations
- 2009Influence of the Spinning Conditions on the Structure and Properties of Polyamide 12/Carbon Nanotube Composite Fiberscitations
- 2009Influence of the Spinning Conditions on the Structure and Properties of Polyamide 12/Carbon Nanotube Composite Fiberscitations
- 2009Kinetics of Nanotube and Microfiber Scission under Sonicationcitations
- 2009Kinetics of nanotube and microfiber scission under sonicationcitations
- 2008High-Conductivity Polymer Nanocomposites Obtained by Tailoring the Characteristics of Carbon Nanotube Fillerscitations
- 2007Shape and Temperature Memory of Nanocomposites with Broadened Glass Transitioncitations
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article
Conductivity and percolation of nanotube based polymer composites in extensional deformations
Abstract
Anisotropic conductive particles are ideal fillers to achieve electrical conductivity in polymer composites. Polymer processing is generally associated to the development of flow fields. It has been observed that flow yields an increase in resistivity. This increase is ascribed to the rotation and flow induced alignment of the particles. Indeed alignment lowers the inter-particle contact probability and thereby the conductivity of the material. The effect of laminar shear has been the topic of several studies over the last years. However, the contribution of elongational flow remains vague in spite of its ubiquity in polymer processing. We report an experimental study in which the contribution of elongational flow and extension is isolated. It is found that the resistivity of extruded composites displays a quadratic increase as a function of the draw ratio. A simple model that considers the relative translation of the particles accounts for this behavior and reveals that translation has much more dramatic consequences than rotation on the conductivity and percolation of nanocomposites