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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fichet, Odile
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Correlation between Ionic Conductivity and Mechanical Properties of Solid-like PEO Polymer Electrolytecitations
- 2016DEVELOPMENT OF A MULTIFUNCTIONAL POLYSILOXANE BASED CONSERVATION TREATMENT FOR BRITTLE PAPER: THE APPLICATION TO AGED NEWSPRINT
- 2014A new conservation treatment for strengthening and deacidification of paper using polysiloxane networks
- 2014DEVELOPMENT OF A NEW POLYMER GLASS WITH ENHANCED RESISTANCE TOWARDS SCRATCHES AND SOLVENT FOR CULTURAL HERITAGE
- 2013Polyelectrolyte/fluorinated polymer interpenetrating polymer networks as fuel cell membranecitations
- 2013Conservation Treatment of Newsprint Paper by Polysiloxanes. Study of interpenetrating networks for strengthening and deacidification (CoMPresSil project)
- 2006Polyisobutene/polycyclohexyl methacrylate interpenetrating polymer networkscitations
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article
Polyisobutene/polycyclohexyl methacrylate interpenetrating polymer networks
Abstract
Interpenetrating polymer networks (IPNs) combining polyisobutene (PIB) and poly(cyclohexyl methacrylate) (PCHMA) networks were prepared using an in situ strategy. PIB networks were formed by alcoholeisocyanate addition between the hydroxyl end groups of telechelic dihydroxypolyisobutene and an isocyanate cross-linker, catalyzed by dibutyltindilaurate (DBTDL). PCHMA networks were obtained from free-radical copolymerization of cyclohexyl methacrylate (CHMA) with ethylene glycol bismethacrylate (EGDM) in the presence of dicyclohexyl peroxydicarbonate (DCPD) as the initiator. The network formations into the IPN architecture were followed by FTIR spectroscopy. In a large composition range, transparent IPNs exhibit two mechanical relaxation temperatures as determined by dynamic mechanical thermal analysis (DMTA), corresponding to those of a PIB enriched phase and of one interpenetrating phase containing the PCHMA network. This morphology was confirmed by IPN surface analysis by AFM. As expected, mechanical properties of PIB networks are improved by the presence of PCHMA network in such IPN architectures.