Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Laven, Jozua

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (4/4 displayed)

  • 2019Design of dual hydrophobic–hydrophilic polymer networks for highly lubricious polyether-urethane coatings13citations
  • 2019Synthesis and rheological characterization of latexes stabilized by methacrylic acid containing macromonomers10citations
  • 2014A simulation approach to study photo-degradation processes of polymeric coatings36citations
  • 2006Influence of catalyst type on the curing process and network structure of alkyd coatings27citations

Places of action

Chart of shared publication
Govers, Stefan P. W.
1 / 3 shared
De With, Gijsbertus
2 / 12 shared
Albers, Peter T. M.
1 / 1 shared
Van Benthem, Rolf A. T. M.
1 / 5 shared
Esteves, A. Catarina C.
1 / 7 shared
Van Herk, Alexander M.
1 / 1 shared
Schreur-Piet, Ingeborg
1 / 6 shared
Heuts, Johan P. A.
1 / 11 shared
Van, R. A. T. M. Benthem
1 / 1 shared
Van Der, L. G. J. Ven
1 / 1 shared
Makki, Hesam
1 / 3 shared
Peters, Frank
1 / 6 shared
Adema, K. N. S.
1 / 1 shared
Pel, Leo
1 / 6 shared
Huinink, Hp Henk
1 / 17 shared
Kopinga, K.
1 / 3 shared
Erich, Bart
1 / 3 shared
Chart of publication period
2019
2014
2006

Co-Authors (by relevance)

  • Govers, Stefan P. W.
  • De With, Gijsbertus
  • Albers, Peter T. M.
  • Van Benthem, Rolf A. T. M.
  • Esteves, A. Catarina C.
  • Van Herk, Alexander M.
  • Schreur-Piet, Ingeborg
  • Heuts, Johan P. A.
  • Van, R. A. T. M. Benthem
  • Van Der, L. G. J. Ven
  • Makki, Hesam
  • Peters, Frank
  • Adema, K. N. S.
  • Pel, Leo
  • Huinink, Hp Henk
  • Kopinga, K.
  • Erich, Bart
OrganizationsLocationPeople

article

Influence of catalyst type on the curing process and network structure of alkyd coatings

  • Laven, Jozua
  • Pel, Leo
  • Huinink, Hp Henk
  • Kopinga, K.
  • Erich, Bart
Abstract

Recent studies have shown that cobalt catalysts, used for curing of alkyd coatings, are potentially carcinogenic, and hence replacement by new environmental friendly catalysts is needed. The influence of different metal based catalysts on the oxidation process has been studied extensively in model systems, consisting of unsaturated oils. However, these results may not be representative for real coatings, since in these systems the oxygen diffusion is much lower than in model systems and therefore may have a large effect on the curing. In this paper, we will show how the curing of an alkyd coating depends on the type of catalyst (cobalt or manganese based). The curing process is studied using a high spatial resolution nuclear magnetic resonance (NMR) setup. The final network structure and cross-link density are found to be correlated with the catalyst used, i.e. a cobalt based catalyst and two manganese based catalysts. The difference in final network structure is investigated by NMR T2 relaxation analysis and the glass transition temperature Tg measured using a differential scanning calorimeter (DSC). In case of the cobalt based catalyst a cross-linking front was observed and a high cross-link density was found, compared to the manganese based catalysts, in which case no sharp cross-linking front was observed. To interpret the observed NMR profiles in more detail, simulations based on a reaction-diffusion model were performed. From the results of these simulations estimates were obtained for the reaction constants and the diffusion of oxygen for the different catalysts

Topics
  • density
  • impedance spectroscopy
  • simulation
  • Oxygen
  • glass
  • glass
  • thermogravimetry
  • glass transition temperature
  • differential scanning calorimetry
  • cobalt
  • Nuclear Magnetic Resonance spectroscopy
  • Manganese
  • curing