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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Muir, Benjamin Ward
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023New insight into degradation mechanisms of conductive and thermally resistant polyaniline filmscitations
- 2023Solvent-free Surface Modification of Milled Carbon Fiber using Resonant Acoustic Mixing
- 2023Comparison of Tiling Artifact Removal Methods in Secondary Ion Mass Spectrometry Imagescitations
- 2023Two-Dimensional and Three-Dimensional Time-of-Flight Secondary Ion Mass Spectrometry Image Feature Extraction Using a Spatially Aware Convolutional Autoencodercitations
- 2023Exploring the Relationship between Polymer Surface Chemistry and Bacterial Attachment Using ToF‐SIMS and Self‐Organizing mapscitations
- 2022Applications of multivariate analysis and unsupervised machine learning to ToF-SIMS images of organic, bioorganic, and biological systems
- 2020ToF-SIMS and machine learning for single-pixel molecular discrimination of an acrylate polymer microarray
- 2017Determining the limit of detection of surface bound antibodycitations
- 2015Fundamentals and functional applications of plasma polymer films
- 2012A ToF-SIMS and XPS study of protein adsorption and cell attachment across PEG-like plasma polymer films with lateral compositional gradients
- 2012One step multifunctional micropatterning of surfaces using asymmetric glow discharge plasma polymerisation
- 2012UV grafting of a vinyl monomer onto a methanol plasma polymercitations
- 2010High-Throughput synthesis and screening of self assembled nanoparticles for use as MRI contrast agents (conference poster)
- 2006X-ray and neutron reflectometry study of glow-discharge plasma polymer filmscitations
Places of action
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article
New insight into degradation mechanisms of conductive and thermally resistant polyaniline films
Abstract
Conductive polyaniline (PANI) coatings find application in various fields, such as electrostatic dissipation, anticorrosion coatings, actives delivery, batteries, and solar control. Improving the thermal and electrical stability of PANI coatings at high temperatures and challenging environments is of growing interest. In this study, a novel polymer blend formulation was developed by adding polyurethane (PU) and sulfonyldiphenol (SDP) to a dinonylnaphthalene sulfonic acid (DNNSA)-doped PANI matrix. Films of the PANI-PU/SDP formulation and unmodified PANI control films were prepared on ITO glass substrates using spin coating, followed by thermal treatment. Characterization of the films was performed using thermogravimetric analysis-mass spectrometry (TGA-MS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) with depth profiling. Results showed that unmodified PANI films aged at 150 °C exhibited rapid thermo-oxidative degradation, resulting in a significant loss in electrical conductivity after 24 h. The inclusion of PU and SDP remarkably improved the thermal stability of the films, maintaining desirable conductivity levels over a week. ToF-SIMS depth profiling helped identify potential degradation mechanisms and monitor changes in chemical composition throughout the film thickness. This study provides insights into the functionality, optimization, and deployment of these new film types.