| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Arhant, Mael
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024Degradation mechanisms in PBSAT nets immersed in seawatercitations
- 2024Basalt fibre degradation in seawater and consequences for long term composite reinforcementcitations
- 2024Basalt fibre degradation in seawater and consequences for long term composite reinforcementcitations
- 2024Compression and hydrothermal ageing after impact of carbon fibre reinforced epoxy laminatescitations
- 2023Non-Arrhenian Hydrolysis of Polyethylene Terephthalate – a 5-year Long Aging Study Above and Below The Glass Transition Temperaturecitations
- 2022Hydrolytic degradation of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) - Towards an understanding of microplastics fragmentationcitations
- 2022Hydrolytic degradation of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) - Towards an understanding of microplastics fragmentationcitations
- 2022Material and structural testing to improve composite tidal turbine blade reliabilitycitations
- 2022Chemical coupling between oxidation and hydrolysis in Polyamide 6 - A key aspect in the understanding of microplastic formationcitations
- 2022Chemical coupling between oxidation and hydrolysis in Polyamide 6 - A key aspect in the understanding of microplastic formationcitations
- 2022Fracture test to accelerate the prediction of polymer embrittlement during aging – Case of PET hydrolysiscitations
- 2022Fracture test to accelerate the prediction of polymer embrittlement during aging – Case of PET hydrolysiscitations
- 2021Origin of embrittlement in Polyamide 6 induced by chemical degradations: mechanisms and governing factorscitations
- 2021Origin of embrittlement in Polyamide 6 induced by chemical degradations: mechanisms and governing factorscitations
- 2020Fatigue of improved polyamide mooring ropes for floating wind turbinescitations
- 2019Carbon/polyamide 6 thermoplastic composite cylinders for deep sea applicationscitations
- 2019Carbon/polyamide 6 thermoplastic composite cylinders for deep sea applicationscitations
- 2019Mechanical Behaviour of Composites Reinforced by Bamboo Strips, Influence of Seawater Agingcitations
- 2019Compréhension de la formation des Microplastiques : Impact de l’hydrolyse du polyamide 6 sur les propriétés à la rupture
- 2019Thermoplastic matrix composites for marine applicationscitations
- 2019Comportement Mécanique de Composites Renforcés de Lamelles de Bambou, Influence du Vieillissement dans l’Eau de Mer ; Mechanical Behaviour of Composites Reinforced by Bamboo Strips, Influence of Seawater Agingcitations
- 2019Fatigue Behaviour of Acrylic Matrix Composites: Influence of Seawatercitations
- 2019Impact of hydrolytic degradation on mechanical properties of PET - Towards an understanding of microplastics formationcitations
- 2018Residual Strains using Integrated Continuous Fiber Optic Sensing in Thermoplastic Composites and Structural Health Monitoringcitations
- 2018Durability of Polymers and Composites: The Key to Reliable Marine Renewable Energy Productioncitations
- 2017Yield stress changes induced by water in polyamide 6: Characterization and modelingcitations
- 2016Modelling the non Fickian water absorption in polyamide 6citations
- 2016Thermoplastic Composites for Underwater Applications
- 2016Effect of sea water and humidity on the tensile and compressive properties of carbon-polyamide 6 laminatescitations
- 2015Thermoplastic matrix composites for underwater applications
Places of action
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article
Hydrolytic degradation of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) - Towards an understanding of microplastics fragmentation
Abstract
The long-term behaviour of PBAT subjected to hydrolytic ageing is investigated in this paper. Samples were aged in water at several temperatures ranging from 80 to 100°C for different durations. Changes in physico-chemical properties were investigated through NMR, GPC, DSC and X-Ray analyses and embrittlement was assessed by tensile tests. It is demonstrated that hydrolysis of PBAT occurs first on the ester group located between the terephthalate and adipate groups leading to a decrease in molar mass. For longer ageing durations, the ester situated within the adipate group undergoes hydrolysis. An increase in crystallinity ratio and a decrease in amorphous layer thickness was observed as consequences of the chain scission process. Finally, a clear change in mechanical behaviour is noted; for the early stages of ageing, the polymer exhibits a ductile behaviour while for longer ageing durations, the polymer is brittle due to a lack of chain entanglement. This transition takes place once the molar mass of PBAT falls below 11 kg/mol, i.e. when a critical molar mass M’c is reached.