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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Liu, Yanwen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Multi-Analytical Study of Damage to Marine Ballast Tank Coatings After Cyclic Corrosion Testing
- 2024High resolution analytical microscopy of damage progression within a polyester powder coating after cyclic corrosion testing
- 2021Local oxidation of the buried epoxy-amine/iron oxide interphasecitations
- 2021Local Oxidation of the Buried Epoxy-Amine / Iron Oxide Interphase
- 2020Examining the early stages of thermal oxidative degradation in epoxy-amine resinscitations
- 2019Leaching from coatings pigmented with strontium aluminium polyphosphate inhibitor pigment- evidence for a cluster-percolation modelcitations
- 2019How pigment volume concentration (PVC) and particle connectivity affect leaching of corrosion inhibitive species from coatingscitations
- 2018Multi-Modal Plasma Focused Ion Beam Serial Section Tomography of an Organic Paint Coatingcitations
- 2017Molecularly Controlled Epoxy Network Nanostructurescitations
- 2017Time-lapse lab-based X-ray nano-CT study of corrosion damagecitations
- 2017An organic coating pigmented with strontium aluminium polyphosphate for corrosion protection of zinc alloy coated steelcitations
- 2017An organic coating pigmented with strontium aluminium polyphosphate for corrosion protection of zinc alloy coated steelcitations
- 2017Influence of Volume Concentration of Active Inhibitor on Microstructure and Leaching Behaviour of a Model Primercitations
- 2016Lithium salts as leachable corrosion inhibitors and potential replacement for hexavalent chromium in organic coatings for the protection of aluminum alloyscitations
- 2016Corrosion inhibition of pure aluminium and AA2014-T6 alloy by strontium chromate at low concentrationcitations
- 2016An investigation of the corrosion inhibitive layers generated from lithium oxalatecontaining organic coating on AA2024-T3 aluminium alloycitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015Protective Film Formation on AA2024-T3 Aluminum Alloy by Leaching of Lithium Carbonate from an Organic Coating
- 2010Corrosion behaviour of mechanically polished AA7075-T6 aluminium alloycitations
- 2006Morphology, composition and structure of anodic films on binary Al-Cu alloyscitations
- 2002Imaging XPS investigation of the lateral distribution of copper inclusions at the abraded surface of 2024T3 aluminium alloy and adsorption of decyl phosphonic acidcitations
Places of action
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article
Examining the early stages of thermal oxidative degradation in epoxy-amine resins
Abstract
Epoxy-amine resins continue to find widespread use as the binders in protective and decorative organic coatings, as the matrix in composite materials, and as adhesives. In service, exposure to the environment ultimately results in oxidative deterioration of these materials, limiting the performance lifetime. Defining this auto-oxidation process is therefore a key challenge in developing more durable high-performance materials. In this study, we investigate oxidative degradation of a model resin based on diglycidyl ether of bisphenol-A (DGEBA) and an aliphatic amine hardener, triethylenetetraamine (TETA). Using infrared spectroscopy, we find that prior to the expected detection of formate groups (corresponding to the well-known radical oxidation mechanism of DGEBA), a band at 1658 cm−1 forms, associated with amine cross-linker oxidation. Infrared microspectroscopy, in-situ heated ATR-infrared, Raman spectroscopy and AFM-IR techniques are thus employed to investigate the early stages of resin oxidation and demonstrate strong parallels between the initial stages of cured resin degradation and the auto-oxidation of TETA cross-linker molecules.