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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

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Topics

Publications (85/85 displayed)

  • 2024The effects of property variation on the dripping behaviour of polymers during UL94 test simulated by particle finite element method2citations
  • 2024The effects of property variation on the dripping behaviour of polymers during UL94 test simulated by particle finite element method2citations
  • 2024Correction to "Investigating the changing dynamics of processing, temperature‐based mechanics, and flame retardancy in the transfer of ammonium polyphosphate/inorganic silicate flame retardants from epoxy resins to glass fiber composites"citations
  • 2024Char, gas, and action: Transfer of the flame-retardant modes of action in epoxy resins and their fiber-reinforced composites5citations
  • 2024Investigating the changing dynamics of processing, temperature-based mechanics, and flame retardancy in the transfer of ammonium polyphosphate/inorganic silicate flame retardants from epoxy resins to glass fiber composites4citations
  • 2024A systematic investigation of the transfer of polyphosphate/inorganic silicate flame retardants from epoxy resins to layered glass fiber-reinforced composites and their post-furnace flexural properties6citations
  • 2024A systematic investigation of the transfer of polyphosphate/inorganic silicate flame retardants from epoxy resins to layered glass fiber‐reinforced composites and their post‐furnace flexural properties6citations
  • 2024Improving the Flame Retardancy of Aluminium Trihydroxide in Thermoplastic Starch Biocomposites Using Waste Fibers and Silicon-Based Synergists2citations
  • 2024Investigating the trade-off effects of inorganic phosphate/silicate flame retardant content on the fire performance and post-fire flexural mechanics of epoxy/glass fiber compositescitations
  • 2024Weaving Through Fire And Force: Fire Behavior and Modes of Action between Epoxy Resin and Glass Fiber Compositescitations
  • 2024Pyrolysis and flammability of phosphorus based flame retardant pressure sensitive adhesives and adhesive tapes2citations
  • 2023Adapting intumescent/low-melting glass flame-retardant formulations for transfer to glass-fiber-reinforced composites and postfiremechanical analysiscitations
  • 2023The quantification of anisotropy in graphene/natural rubber nanocomposites: Evaluation of the aspect ratio, concentration, and crosslinking2citations
  • 2023SHAPE, ORIENTATION, INTERACTION, OR DISPERSION: VALORIZATION OF THE INFLUENCE FACTORS IN NATURAL RUBBER NANOCOMPOSITES8citations
  • 2023Influence of the Size and Dispersion State of Two-Dimensional Nanomaterials on the Fire Safety of Polymerscitations
  • 2023Shape, orientation, interaction, or dispersion: valorization of the influence factors in natural rubber nanocomposites8citations
  • 2023Adapting intumescent/low-melting glass flame-retardant formulations for transfer to glass-fiber-reinforced composites and post-fire mechanical analysiscitations
  • 2022Networking Skills: The Effect of Graphene on the Crosslinking of Natural Rubber Nanocomposites with Sulfur and Peroxide Systems5citations
  • 2022Multifunctional Property Improvements by Combining Graphene and Conventional Fillers in Chlorosulfonated Polyethylene Rubber Composites15citations
  • 2022Valorizing “non-vegan” bio-fillers: Synergists for phosphorus flame retardants in epoxy resins36citations
  • 2021Multifunctional graphene nanofiller in flame retarded polybutadiene/chloroprene/carbon black composites19citations
  • 2021Bench-scale fire stability testing - Assessment of protective systems on carbon fibre reinforced polymer composites16citations
  • 2020Intrinsic flame retardant phosphonate-based vitrimers as a recyclable alternative for commodity polymers in composite materials50citations
  • 2020Evaluation of thermoanalytical methods equipped with evolved gas analysis for the detection of microplastic in environmental samples73citations
  • 2020Dripping and decomposition under fire: Melamine cyanurate vs. glass fibres in polyamide 630citations
  • 2020Particle Size Related Effects of Multi-Component Flame-Retardant Systems in poly(butadiene terephthalate)9citations
  • 2019Matrix matters35citations
  • 2019Multilayer Graphene/Elastomer Nanocompositescitations
  • 2019Matrix matters: Hyperbranched flame retardants in aliphatic and aromatic epoxy resins35citations
  • 2019Industrial-waste agave fibres in flame-retarded thermoplastic starch biocomposites45citations
  • 2018Graphene / hydrogenated acrylonitrile-butadiene rubber nanocomposites: Dispersion, curing, mechanical reinforcement, multifunctional filler44citations
  • 2018Phosphorus-containing polymer flame retardants for aliphatic polyesters17citations
  • 2017Variation of intumescent coatings revealing different modes of action for good protection performance46citations
  • 2017Polylactic acid biocomposites: approaches to a completely green flame retarded polymer45citations
  • 2017Fire stability of glass-fibre sandwich panels: The influence of core materials and flame retardants41citations
  • 2017Intumescent geopolymer-bound coatings for fire protection of steelcitations
  • 2017Fire stability of carbon fiber reinforced polymer shells on the intermediate-scale43citations
  • 2017The effect of traditional flame retardants, nanoclays and carbon nanotubes in the fire performance of epoxy resin composites48citations
  • 2016Influence of a novel organo-silylated clay on the morphology, thermal and burning behavior of low density polyethylene composites52citations
  • 2016Multilayer graphene chlorine isobutyl isoprene rubber nanocomposites: influence of the multilayer graphene concentration on physical and flame-retardant properties21citations
  • 2016Aluminium diethylphosphinate versus ammonium polyphosphate: A comprehensive comparison of the chemical interactions during pyrolysis in flame-retarded polyolefine/poly(phenylene oxide)citations
  • 2016Multilayer graphene/chlorine-isobutene-isoprene rubber nanocomposites: the effect of dispersion29citations
  • 2016The synergistic effect of organically modified sepiolite in intumescent flame retardant polypropylene118citations
  • 2016Multilayer Graphene/Carbon Black/Chlorine Isobutyl Isoprene Rubber Nanocomposites33citations
  • 2016Melamine poly(metal phosphates) as flame retardant in epoxy resin: Performance, modes of action, and synergy68citations
  • 2016Multilayer graphene rubber nanocomposites1citations
  • 2015Carbon-based nanofillers/poly(butylene terephthalate): thermal, dielectric, electrical and rheological properties15citations
  • 2015The influence of layered, spherical, and tubular carbon nanomaterials' concentration on the flame retardancy of polypropylene84citations
  • 2015Multifunctional multilayer graphene/elastomer nanocomposites49citations
  • 2015Protecting the structural integrity of composites in fire: Intumescent coatings in the intermediate scale15citations
  • 2014Nanotechnology finding its way into flame retardancy3citations
  • 2013Carbon black, multiwall carbon nanotubes, expanded graphite and functionalized graphene flame retarded polypropylene nanocomposites140citations
  • 2013Effect of well dispersed amorphous silicon dioxide in flame retarded styrene butadiene rubber27citations
  • 2013Influence of polymeric flame retardants based on phosphorus-containing polyesters on morphology and material characteristics of poly(butylene terephthalate)25citations
  • 2013An intermediate-scale fire testing approach on the structural integrity of lightweight materialscitations
  • 2012Structure-property relationships of halogen-free flame-retarded poly(butylene terephthalate) and glass fiber reinforced PBT27citations
  • 2012Flammability of layered silicate epoxy nanocomposites combined with low-melting inorganic ceepree glass34citations
  • 2012Structure−property relationships of halogen‐free flame‐retarded poly(butylene terephthalate) and glass fiber reinforced PBT27citations
  • 2012Synthesis, properties, and processing of new siloxane-substituted poly(p-xylylene) via CVD14citations
  • 2012SEM/EDX: Advanced investigation of structured fire residues and residue formation44citations
  • 2012Experimental and quantitative assessment of flame retardancy by the shielding effect in layered silicate epoxy nanocomposites78citations
  • 2012Synergistic fire retardancy in layered-silicate nanocomposite combined with low-melting phenysiloxane glass49citations
  • 2011Layered silicate epoxy nanocomposites: formation of the inorganic-carbonaceous fire protection layer113citations
  • 2011A new halogen-free flame retardant based on 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide for epoxy resins and their carbon fiber composites for the automotive and aviation industries161citations
  • 2011Flame retardant biocomposites: Synergism between phosphinate and nanometric metal oxides131citations
  • 2011Fire retardancy in composites: a journey from nano to intermediate scalecitations
  • 2011Fire retardant synergisms between nanometric Fe2O3 and aluminium phosphinate in poly(butylene terephthalate)111citations
  • 2011Novel DOPO-based flame retardants in high-performance carbon fibre epoxy composites for aviation334citations
  • 2010Flame retarded epoxy resins by adding layered silicate in combination with the conventional protection-layer-building flame retardants melamine borate and ammonium polyphosphate68citations
  • 2010Solid-state NMR on thermal and fire residues of bisphenol A polycarbonate/silicone acrylate rubber/bisphenol A bis(diphenyl-phosphate)/(PC(SiR/BDP) and PC/SiR/BDP/zinc borate (PC/SiR/BDP/ZnB) - Part II: The influence of SiR26citations
  • 2010Temperature inside burning polymer specimens: Pyrolysis zone and shielding68citations
  • 2009Halogen-free flame retarded poly(butylene terephthalate) (PBT) using metal oxides/PBT nanocomposites in combination with aluminium phosphinate183citations
  • 2008Flame retardancy mechanisms of aryl phosphates in combination with boehmite in bisphenol A polycarbonate/acrylonitrile-butadiene-styrene blends111citations
  • 2007Novel Phosphorus-containing Hardeners with Tailored Chemical Structures for Epoxy Resins: Synthesis and Cured Resin Propertiescitations
  • 2007Pyrolysis of Epoxy Resins and Fire Behavior of Epoxy Resin Composites Flame-Retarded with 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide Additivescitations
  • 2007Solid-state NMR investigations of the pyrolysis and thermo-oxidative decomposition products of a polystyrene/red phosphorus/magnesium hydroxide systemcitations
  • 2007Novel phosphorus-modified polysulfone as a combined flame retardant and toughness modifier for epoxy resinscitations
  • 2006Some comments on the main fire retardancy mechanisms in polymer nanocomposites227citations
  • 2006Phosphonium-modified layered silicate epoxy resins nanocomposites and their combinations with ATH and organo-phosphorus fire retardants114citations
  • 2005Fire behaviour of polyamide 6/multiwall carbon nanotube naocomposites290citations
  • 2005Dielectric Study of Molecular Mobility in Poly(propylene-graft-maleic anhydride)/Clay Nanocomposites113citations
  • 2004Layered silicate polymer nanocomposites: new approach or illusion for fire retardancy? Investigations of the potentials and the tasks using a model systemcitations
  • 2003Polypropylene-graft-maleic anhydride-nanocomposites: I-Characterization and thermal stability of nanocomposites produced under nitrogen and in air87citations
  • 2003Fire Retardancy Mechanisms of Red Phosphorus in Thermoplasticscitations
  • 2002Red Phosphorus-Controlled Decomposition for Fire Retardant PA 66101citations

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Diniz, Analice Turski Silva
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Ruckdäschel, H.
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Jauregui Rozo, Maria
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Inasu, S.
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Huth, Christian
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Tabaka, Weronika
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Medina, L.
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Lauterbach, Tobias
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Timme, Sebastian
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Berglund, L. A.
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Duquesne, S.
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Markwart, Jens C.
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Wurm, Frederik R.
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Koschek, Katharina
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Urbaniak, Tobias
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Haag, Katharina
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Braun, Ulrike
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Wolf, Michael
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Co-Authors (by relevance)

  • Diniz, Analice Turski Silva
  • Turski Silva Diniz, Analice
  • Ruckdäschel, H.
  • Jauregui Rozo, Maria
  • Inasu, S.
  • Sunder, S.
  • Inasu, Sneha
  • Sunder, Sruthi
  • Ruckdäschel, Holger
  • Rozo, Maria Jauregui
  • Sanchez Olivares, G.
  • Rockel, Daniel
  • Flothmeier, K.
  • Hupp, Vitus
  • Hartwig, A.
  • Strommer, Bettina
  • Schulze, Dietmar
  • Böhning, Martin
  • Battig, Alexander
  • Jácome, Leonardo Agudo
  • Agudo Jácome, Leonardo
  • Huth, Christian
  • Frasca, Daniele
  • Garfias González, Karla I.
  • Abdou-Rahaman Fadul, Naïssa
  • Carosio, F.
  • Tabaka, Weronika
  • Medina, L.
  • Lauterbach, Tobias
  • Timme, Sebastian
  • Berglund, L. A.
  • Duquesne, S.
  • Markwart, Jens C.
  • Wurm, Frederik R.
  • Koschek, Katharina
  • Urbaniak, Tobias
  • Haag, Katharina
  • Goedecke, Caroline
  • Eisentraut, Paul
  • Wiesner, Yosri
  • Klack, Patrick
  • Dittmann, Daniel
  • Braun, Ulrike
  • Drummer, Dietmar
  • Tomiak, Florian
  • Wolf, Michael
  • Wurm, F. R.
  • Markwart, J. C.
  • Pérez-Chávez, R.
  • Rabe, Sebastian
  • Calderas, F.
  • Sanchez-Olivares, G.
  • Zirnstein, Benjamin
  • Pospiech, D.
  • Häußler, L.
  • Korwitz, A.
  • Schwarzer, M.
  • Dittrich, Bettina
  • Komber, H.
  • Sturm, Heinz
  • Illerhaus, Bernhard
  • Morys, Michael
  • Çiftci, Serhat
  • Gallo, Emanuela
  • Sypaseuth, Fanni D.
  • Trappe, Volker
  • Hörold, Andreas
  • Bünker, J.
  • Korzen, Manfred
  • Sturm, Patrick
  • Watolla, Marie-Bernadette
  • Krüger, Simone
  • Gluth, Gregor
  • Rickard, W. D. A.
  • Pereira, C. M. C.
  • Magalhães, F. D.
  • Martins, M. S. S.
  • Incarnato, L.
  • Scarfato, Paola
  • Di Maio, L.
  • Krafft, Bernd
  • Sut, Aleksandra
  • Jäger, Christian
  • Greiser, Sebastian
  • Wachtendorf, Volker
  • Acierno, Domenico
  • Pappalardo, Salvatore
  • Russo, Pietro
  • Rybak, Thomas
  • Müller, Patrick
  • Wartig, K.-A.
  • Kerling, S.
  • Farooq, Muhammad
  • Hofmann, D.
  • Yin, Huajie
  • Schönhals, Andreas
  • Okolieocha, C.
  • Altstädt, V.
  • Mülhaupt, R.
  • Gettwert, Volker
  • Schmaucks, G.
  • Döring, M.
  • Wolff-Fabris, F.
  • Fischer, O.
  • Brehme, Sven
  • Köppl, T.
  • Wu, Guang Mei
  • Kleemeier, M.
  • Köppl, Thomas
  • Altstädt, Volker
  • Döring, Manfred
  • Wolfffabris, Felipe
  • Bier, A. K.
  • Greiner, A.
  • Bognitzki, M.
  • Schmidt, A.
  • Weiß, André
  • Yu, D.
  • Bahr, Horst
  • Fischer, R. X.
  • Vogt, C.
  • Krämer, J.
  • Stöß, K.
  • Ciesielski, M.
  • Perret, Birgit
  • Diederichs, J.
  • Russo, P.
  • Mohr, F.
  • Wawrzyn, Eliza
  • Karrasch, Andrea
  • Pawlowski, Kristin
  • Artner, J.
  • Hoffmann, T.
  • Balabanovich, Aliaksandr
  • Perez, R. M.
  • Knoll, Uta
  • Sandler, J. K. W.
  • Perez, R.
  • Fichera, Mario Augusto
  • Bartholmai, Matthias
  • Pütz, D.
  • Pötschke, P.
  • Abdel-Goad, M.
  • Brzezinka, Klaus-Werner
  • Goering, Harald
  • Turky, Gamal
  • Fritz, Andreas
  • Hentschel, Manfred P.
  • Tidjani, Adams
  • Pohl, M.-M.
  • Wald, Oliver
  • Neubert, Dietmar
  • Kunze, Ralf
OrganizationsLocationPeople

article

Matrix matters

  • Markwart, Jens C.
  • Wurm, Frederik R.
  • Battig, Alexander
  • Schartel, Bernhard
Abstract

<p>We synthesized a library of phosphorus-based flame retardants (phosphates and phosphoramides of low and high molar mass) and investigated their behavior in two epoxy resins (one aliphatic and one aromatic). The pyrolytic and burning behavior of the two resins (via TGA, TG-FTIR, Hot stage FTIR, Py-GC/MS, PCFC, DSC, LOI, UL-94, Cone calorimeter) are analyzed and compared to the results of flame retardant (FR)-containing composites. A decomposition pathway incorporating the identified modes of action and known chemical mechanisms is proposed. The overlap of decomposition temperature (T<sub>dec</sub>) ranges of matrix and FR determines the efficacy of the system. Low molar mass FRs strongly impact material properties like T<sub>g</sub> but are very reactive, and high molar mass variants are more thermally stable. Varying P–O and P–N content of the FR affects decomposition, but the chemical structure of the matrix also guides FR behavior. Thus, phosphates afford lower fire load and heat release in aliphatic epoxy resins, and phosphoramides can act as additives in an aromatic matrix or a reactive FRs in aliphatic ones. The chemical structure and the structure-property relationship of both FR and matrix are central to FR performance and must be viewed not as two separate but as one codependent system.</p>

Topics
  • impedance spectroscopy
  • reactive
  • composite
  • mass spectrometry
  • thermogravimetry
  • differential scanning calorimetry
  • resin
  • decomposition
  • Phosphorus
  • pyrolysis gas chromatography