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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rautkari, Lauri
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2023Improving mechanical performance and functionality of birch veneer with mechano-enzymatic microfibrillated cellulose coatingcitations
- 2023Evaluating the quality of surface carbonized woods modified with a contact charring or a gas flame charring techniquecitations
- 2022Decay Resistance of Surface Carbonized Woodcitations
- 2022Effect of Moisture on Polymer Deconstruction in HCl Gas Hydrolysis of Woodcitations
- 2022Moisture Sorption of Wood Surfaces Modified by One-Sided Carbonization as an Alternative to Traditional Façade Coatingscitations
- 2021Bioinspired living coating system in service: evaluation of the wood protected with biofinish during one-year natural weatheringcitations
- 2021Deswelling of microfibril bundles in drying wood studied by small-angle neutron scattering and molecular dynamicscitations
- 2021Water-accessibility of interfibrillar spaces in spruce wood cell wallscitations
- 2021Thermal modification of wood—a review: chemical changes and hygroscopicitycitations
- 2020Observing microfibril bundles in wood by small-angle neutron scattering
- 2020The effect of compression and incision on wood veneer and plywood physical and mechanical propertiescitations
- 2020Bundling of cellulose microfibrils in native and polyethylene glycol-containing wood cell walls revealed by small-angle neutron scatteringcitations
- 2020Effect of weathering on surface functional groups of charred norway spruce cladding panelscitations
- 2020Moisture-related changes in the nanostructure of woods studied with X-ray and neutron scatteringcitations
- 2020Resistance of thermally modified and pressurized hot water extracted Scots pine sapwood against decay by the brown-rot fungus Rhodonia placentacitations
- 2019Small-angle scattering model for efficient characterization of wood nanostructure and moisture behaviourcitations
- 2018The effect of de- and re-polymerization during heat-treatment on the mechanical behavior of Scots pine sapwood under quasi-static loadcitations
- 2018Sorption-related characteristics of surface charred spruce woodcitations
- 2018Influence of water and humidity on wood modification with lactic acidcitations
- 2018Thermal Isomerization of Hydroxyazobenzenes as a Platform for Vapor Sensingcitations
- 2018Thermal Isomerization of Hydroxyazobenzenes as a Platform for Vapor Sensingcitations
- 2017THE INFLUENCE OF THERMAL MODIFICATION ON VENEER BOND STRENGTH
- 2017Surface activation of wood by corona treatment and NaOH soaking for improved bond performance in plywoodcitations
- 2017Influence of temperature of thermal treatment on surface densification of sprucecitations
- 2017Pre-treatment with sodium silicate, sodium hydroxide, ionic liquids or methacrylate resin to reduce the set-recovery and increase the hardness of surface-densified scots pinecitations
- 2016Cladding boards in wooden facades
- 2015Influence of Welding Time on Tensile-Shear Strength of Linear Friction Welded Birch (Betula pendula L.) Woodcitations
- 2015High-Strength Composite Fibers from Cellulose-Lignin Blends Regenerated from Ionic Liquid Solutioncitations
- 2014Internal vapour pressure of plywood during hot pressing process (STSM funded by COST Action FP1006)
Places of action
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article
The effect of de- and re-polymerization during heat-treatment on the mechanical behavior of Scots pine sapwood under quasi-static load
Abstract
<p>Loss in strength and ductility is a major drawback for the heat-treatment of solid wood. Previous studies focused mainly on the de-polymerization of cell wall constituents as a cause and the importance of the preferential removal of hemicelluloses. This study tested the hypothesis that the mechanical behavior of wood is additionally affected by re-polymerization reactions within the cell wall matrix during heat-treatment. This was achieved by comparing changes in chemical composition, FT-IR spectra, and mechanical properties of Scots pine sapwood that was heat-treated in either dry state in superheated steam or in wet state using pressurized hot water. Although preferential de-polymerization of hemicelluloses was evident for both heat-treatment techniques, the analysis of the chemical composition and FT-IR spectroscopy indicated additional re-polymerization reactions within the cell wall matrix of dry heat-treated wood. The consequent formation of covalent bonds and cross-links increased the resistance against compression loads and hindered inelastic deformation during bending. This resulted in an additional reduction in bending strength and strain energy density of dry compared to wet heat-treated wood. Re-polymerization reactions during heat-treatments of wood in dry state were suggested as the main cause for the brittle failure under bending loads, while the effect of hemicellulose-removal on brittleness was much smaller than stated previously.</p>