| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Al-Malaika, Sahar
Aston University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2021Influence of anti-ageing compounds on rheological properties of bitumencitations
- 2021Effect of processing conditions and catalyst type on the thermal oxidative degradation mechanisms and melt stability of metallocene and Ziegler‐catalyzed ethylene‐1‐hexene copolymerscitations
- 2021New and novel stabilisation approach for radiation-crosslinked Ultrahigh Molecular Weight Polyethylene (XL-UHMWPE) targeted for use in orthopeadic implantscitations
- 2020Photo-stabilization of biopolymers-based nanocomposites with UV-modified layered silicatescitations
- 2017Novel strategic approach for the thermo- and photo-oxidative stabilization of polyolefin/clay nanocompositescitations
- 2017Novel strategic approach for the thermo- and photo- oxidative stabilization of polyolefin/clay nanocompositescitations
- 2017Thermo-oxidative stabilization of poly(lactic acid)-based nanocomposites through the incorporation of clay with in-built antioxidant activitycitations
- 2015Novel organo-modifier for thermally-stable polymer-layered silicate nanocompositescitations
- 2013Influence of processing and clay type on nanostructure and stability of polypropylene-clay nanocompositescitations
- 2011Effect of contact surfaces on the thermal and photoxidation of dehydrated castor oilcitations
- 2010Reactive processing of polymerscitations
- 2009Effect of extrusion and photo-oxidation on polyethylene/clay nanocompositescitations
- 2009Reactive processing of polymers: structural characterization of products by 1H and 13C NMR spectroscopy for glycidyl methacrylate grafting onto EPR in the absence and presence of a reactive comonomercitations
- 2008Special issue of PDS - Based on PDDG meeting, Aston University, September 2007, in honour of Professor Norman Billingham
- 2006Metallocene ethylene-1-octene copolymerscitations
- 2005Polymer degradation and stabilitycitations
- 2004Perspectives in stabilisation of polyolefinscitations
- 2003Oxidative degradation and stabilisation of polymerscitations
Places of action
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article
Effect of contact surfaces on the thermal and photoxidation of dehydrated castor oil
Abstract
The effect of stainless steel, glass, zirconium and titanium enamel surfaces on the thermal and photooxidative toughening mechanism of dehydrated castor oil films deposited on these surfaces was investigated using different analytical and spectroscopic methods. The conjugated and non-conjugated double bonds were identified and quantified using both Raman spectroscopy and 1D and 2D NMR spectroscopy. The disappearance of the double bonds in thermally oxidised oil-on-surface films was shown to be concomitant with the formation of hydroperoxides (determined by iodometric titration). The type of the surface had a major effect on the rate of thermal oxidation of the oil, but all of the surfaces examined had resulted in a significantly higher rate of oxidation compared to that of the neat oil. The highest effect was exhibited by the stainless steel surface followed by zirconium enamel, titanium enamel and glass. The rate of thermal oxidation of the oil-on-steel surface (at 100 °C, based on peroxide values) was more than five times faster than that of oil-on-glass and more than 21 times faster than the neat oil when compared under similar thermal oxidative conditions. The rate of photooxidation at 60 °C of oil-on-steel films was found to be about one and half times faster than their rate of thermal oxidation at the same temperature. Results from absorbance reflectance infrared microscopy with line scans taken across the depth of thermally oxidised oil-on-steel films suggest that the thermal oxidative toughening mechanism of the oil occurs by two different reaction pathways with the film outermost layers, i.e. furthest away from the steel surface, oxidising through a traditional free radical oxidation process involving the formation of various oxygenated products formed from the decomposition of allylic hydroperoxides, whereas, in the deeper layers closer to the steel surface, crosslinking reactions predominate.