| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Massoud, Salah S.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2023Dinuclear doubly bridged phenoxido copper(II) complexes as efficient anticancer agentscitations
- 2023Structure and magnetic characterization of some bicompartmental [N6O2] divalent metal(ii) complexes using bis(phenolato) ligands bearing two pendant bis(pyridyl) amine arms
- 2023Magnetostructural Properties of Some Doubly-Bridged Phenoxido Copper(II) Complexescitations
- 2023Copper(II) and zinc(II) complexes bridged by benzenoid aromatic oxocarbon and dicarboxylate dianionscitations
- 2021Synthesis, crystal structures, spectral, magnetic and thermal properties of 1-D polymeric dicyanamido-metal(II) complexescitations
- 2021Identification of potent anticancer copper(ii) complexes containing tripodal bis[2-ethyl-di(3,5-dialkyl-1H-pyrazol-1-yl)]amine moietycitations
- 2021Syntheses, structural characterization, and thermal behaviour of metal complexes with 3-aminopyridine as co-ligandscitations
- 2020Polynuclear and coordination polymers of copper(II) complexes assembled by flexible polyamines and bridging rigid N-heterocyclic multicarboxylatescitations
- 2019Azido-cobalt(II) coordination polymers exhibiting slow magnetic relaxation and metamagnetic transitioncitations
- 2019Structure, DFT Calculations, and Magnetic Characterization of Coordination Polymers of Bridged Dicyanamido-Metal(II) Complexescitations
- 2019Synthesis and characterization of 1D coordination polymers of metal(II)-dicyanamido complexescitations
- 2019Thiocyanato-metal(II) and azido-cobalt(III) complexes with hydroxymethylpyridinescitations
- 2017Synthesis, structural characterization and magnetic properties of polymeric azido Mn(II) complexes based on methyl-pyridine-N-oxide co-ligandscitations
- 2017Synthesis, crystal structures, spectral and magnetic properties of 1-D polymeric dicyanamido-metal(II) complexescitations
- 2017Pyridyl and triazole ligands directing the assembling of zinc(II) into coordination polymers with different dimensionality through azides.citations
- 2016Metal(II) complexes of compartmental polynuclear schiff bases containing phenolate and alkoxy groups.citations
- 2016Synthesis, characterization and luminescence properties of zinc(II) and cadmium(II) pseudohalide complexes derived from quinoline-N-oxide.citations
- 2015Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes.citations
- 2015Synthesis, characterization and luminescence properties of zinc(II) complexes of pseudohalides and nitrite derived from 4-azidopyridinecitations
- 2015Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M = Ni, Co, Cd) complexes.citations
- 2015Five-coordinate metal(II) complexes based pyrazolyl ligands.citations
- 2015Synthesis and characterization of five new thiocyanato- and cyanato-metal(II) complexes with 4-azidopyridine as co-ligandcitations
Places of action
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article
Synthesis and characterization of 1D coordination polymers of metal(II)-dicyanamido complexes
Abstract
Five new metal(II) dicyanamido (dca) complexes with 3-aminopyridine (py-NH2) have been synthesized, catena-[M(μ1,5-dca)2(py-NH2)2] {M = Mn (1), Cu (2), Co (3), Zn (4) and Cd (5)}, and characterized by elemental analysis, IR, UV–Vis spectroscopy, single crystal X-ray and powder diffraction, respectively. The isostructural polymeric 1D complexes feature double µ1,5-bridging dicyanamide ligands and two terminal 3-aminopyridine ligands located in a trans-conformation around the distorted M(II) octahedra, which add extra stability through their involvements in the formation of 3D supramolecular hydrogen bonded systems and the constitution of non-covalent π–π ring-ring interactions along the chain direction. The magnetic properties of complexes 1–3 were studied at variable temperature over the range 2–300 K. Luminescence enhancements upon complexation of dca ligands was observed in 4 and 5.