| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Torvisco, Ana
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Synthesis and Characterization of Alkali Metal Hypersilyl Borates
- 2023Dinuclear doubly bridged phenoxido copper(II) complexes as efficient anticancer agentscitations
- 2023Synthesis and Characterization of 3-Aminopropyl-phenyl Germanescitations
- 2023Structure and magnetic characterization of some bicompartmental [N6O2] divalent metal(ii) complexes using bis(phenolato) ligands bearing two pendant bis(pyridyl) amine arms
- 2023Magnetostructural Properties of Some Doubly-Bridged Phenoxido Copper(II) Complexescitations
- 2023Copper(II) and zinc(II) complexes bridged by benzenoid aromatic oxocarbon and dicarboxylate dianionscitations
- 2021Syntheses, structural characterization, and thermal behaviour of metal complexes with 3-aminopyridine as co-ligandscitations
- 2020Synthesis and characterization of zinc di(O-2,2-dimethylpentan-3-yl dithiocarbonates) bearing pyridine or tetramethylethylenediamine coligands and investigation of their thermal conversion mechanisms towards nanocrystalline zinc sulfidecitations
- 2020Polynuclear and coordination polymers of copper(II) complexes assembled by flexible polyamines and bridging rigid N-heterocyclic multicarboxylatescitations
- 2019Structure, DFT Calculations, and Magnetic Characterization of Coordination Polymers of Bridged Dicyanamido-Metal(II) Complexescitations
- 2019Synthesis and characterization of 1D coordination polymers of metal(II)-dicyanamido complexescitations
- 2014Stable Silenolates and Brook-Type Silenes with Exocyclic Structurescitations
- 2014Photoinduced Brook-type Rearrangement of Acylcyclopolysilanescitations
- 2013Bismuth sulphide–polymer nanocomposites from a highly soluble bismuth xanthate precursorcitations
- 2013Synthesis and Properties of Bridgehead-Functionalized Permethylbicyclo[2.2.2]octasilanescitations
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article
Synthesis and characterization of 1D coordination polymers of metal(II)-dicyanamido complexes
Abstract
Five new metal(II) dicyanamido (dca) complexes with 3-aminopyridine (py-NH2) have been synthesized, catena-[M(μ1,5-dca)2(py-NH2)2] {M = Mn (1), Cu (2), Co (3), Zn (4) and Cd (5)}, and characterized by elemental analysis, IR, UV–Vis spectroscopy, single crystal X-ray and powder diffraction, respectively. The isostructural polymeric 1D complexes feature double µ1,5-bridging dicyanamide ligands and two terminal 3-aminopyridine ligands located in a trans-conformation around the distorted M(II) octahedra, which add extra stability through their involvements in the formation of 3D supramolecular hydrogen bonded systems and the constitution of non-covalent π–π ring-ring interactions along the chain direction. The magnetic properties of complexes 1–3 were studied at variable temperature over the range 2–300 K. Luminescence enhancements upon complexation of dca ligands was observed in 4 and 5.