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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Reichmann, Klaus
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Synergistic Homovalent and Heterovalent Substitution Effects on Piezoelectric and Relaxor Behavior in Lead-Free BaTiO3 Ceramicscitations
- 2021Synthesis, crystal structures, spectral, magnetic and thermal properties of 1-D polymeric dicyanamido-metal(II) complexescitations
- 2021High-Resolution Microstructure Characterization of Additively Manufactured X5CrNiCuNb17-4 Maraging Steel during Ex and In Situ Thermal Treatmentcitations
- 2021Syntheses, structural characterization, and thermal behaviour of metal complexes with 3-aminopyridine as co-ligandscitations
- 2020B-site vacancy induced Raman scattering in BaTiO3-based ferroelectric ceramicscitations
- 2020Electrochemical and structural property of TiSiNb TFSOC on affordable interconnects in proton exchange membrane fuel cell applicationscitations
- 2019Thiocyanato-metal(II) and azido-cobalt(III) complexes with hydroxymethylpyridinescitations
- 2018Remarkable impact of low BiYbO3 doping levels on the local structure and phase transitions of BaTiO3citations
- 2015Structure–property relationships in (1 − x)BaTiO3–xBiGdO3 ceramicscitations
- 2015Bismuth Sodium Titanate Based Materials for Piezoelectric Actuatorscitations
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article
Thiocyanato-metal(II) and azido-cobalt(III) complexes with hydroxymethylpyridines
Abstract
A dimeric [Cu(μ-4-HOMP)(4-HOMP)(NCS)2]2 (1) and three discrete monomeric complexes [Ni(3-HOMP)2(NCS)2(H2O)2] (2), [Co(3-HOMP)3(N3)3]·H2O (3) and [Zn(4-HOMP)2(NCS)2] (4), (3-HOMP = 3-hydroxymethylpyridine, 4-HOMP = 4-hydroxymethylpyridine) have been isolated and structurally characterized by IR, UV–Vis spectroscopy, XRPD, single crystal X-ray crystallography and Hirshfeld surface analysis as well as thermogravimetric analyses for complexes 1, 2 and 4. In dimeric complex 1 each penta-coordinated Cu2+ center is bridged through N,O-4-HOMP ligands, whereas metal ions in 2 and 3 are located in distorted octahedral geometry with mer-configuration in the azido complex 3. Distorted tetrahedral geometry is observed around Zn2+ in complex 4. The variable temperature magnetic susceptibility measurements of 1 showed very weak antiferromagnetic interaction.