| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Massoud, S. S.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2016Synthesis, characterization and luminescent properties of polymeric cadmium(II) bridged-thiocyanato and mononuclear thiocyanato-zinc(II) complexes of pyridine-N-oxide derativescitations
- 2016Dinuclear metal(II)-acetato complexes based on bicompartmental 4-chlorophenolate: syntheses, structures, magnetic properties, DNA interactions and phosphodieser hydrolysiscitations
- 2016Synthesis and characterization of polymeric azido Zn(II) and Ni(II) complexes based on 3-hydroxypyridinecitations
- 2016Coordination polymers of azido and thiocyanato Cd(II) and Zn(II) complexes based on 2,6-luidine-N-oxide. Synthesis, characterization and luminescen propertiescitations
Places of action
| Organizations | Location | People |
|---|
article
Synthesis, characterization and luminescent properties of polymeric cadmium(II) bridged-thiocyanato and mononuclear thiocyanato-zinc(II) complexes of pyridine-N-oxide deratives
Abstract
The synthesis and structural characterization of six new d10 Cd(II) and Zn(II) thiocyanato complexes with pyridine-N-oxide compounds: the polymeric catena-[Cd(μ2-2-picoline-N-oxide)(μN,S-NCS)2] (1), catena-[Cd(μ2-3-picoline-N-oxide)(μN,S-NCS)2] (2), catena-[Cd(4-nitropyridine-N-oxide)2(μN,S-NCS)2] (3), the dinuclear [Cd(4-cyanopyridine-N-oxide)2(μN,S-NCS)(NCS)(H2O)]2 (4) and the mononuclear complexes [Zn(2-picoline-N-oxide)2(NCS)2(H2O)] (5) and [Zn(4-cyanopyridine-N-oxide)2(NCS)2(H2O)] (6) are reported. Single crystal X-ray crystallography revealed the 2D polymeric nature in complexes 1 and 2, the 1D chain in 3 and the dimeric structure in complex 4 with the doubly-bridged Cd(μN,S-NCS)2Cd moiety. Five-coordinate monomeric Zn(II) complexes were obtained in 5 and 6, where the thiocyanto ligands are acting as monodentate N-bonded. The emission spectral properties of the six complexes were investigated. Very strong enhancing fluorescence intensity was observed in complex 3.