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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Scherzer, Michael
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2015Synthesis, characterization and luminescence properties of zinc(II) complexes of pseudohalides and nitrite derived from 4-azidopyridinecitations
- 2015Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M = Ni, Co, Cd) complexes.citations
- 2015Synthesis and characterization of five new thiocyanato- and cyanato-metal(II) complexes with 4-azidopyridine as co-ligandcitations
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article
Synthesis and characterization of five new thiocyanato- and cyanato-metal(II) complexes with 4-azidopyridine as co-ligand
Abstract
Five new metal(II) pseudohalide complexes with 4-azidopyridine (4-azpy, 6) were synthesized, [Ni2(4-azpy)6(NCS)4] (1), [Co(4-azpy)4(NCS)2] (2), [Mn(4-azpy)4(NCS)2] (3), [Ni(4-azpy)4(NCO)2] (4), and [Co(4-azpy)2(NCO)2] (5), and characterized by IR, UV-visible spectroscopy and single crystal x-ray diffraction.The crystal structure of the dimeric complex 1 features terminal and μ(N,S)-bridging thiocyanates, and 4-azidopyridine ligands in mer-conformation around the distorted Ni(II) octahedra.The monomeric complexes 2-4 form distorted octahedral MN6 geometries with two N-coordinated terminal pseudohalides in trans-arrangement.The CoN4 tetrahedron in 5 is formed by two cyanate anions and two 4-azidopyridine mols.The magnetic properties of the dimeric complex 1 are reported. [on SciFinder(R)]