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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Scherzer, Michael
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Publications (3/3 displayed)
- 2015Synthesis, characterization and luminescence properties of zinc(II) complexes of pseudohalides and nitrite derived from 4-azidopyridinecitations
- 2015Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M = Ni, Co, Cd) complexes.citations
- 2015Synthesis and characterization of five new thiocyanato- and cyanato-metal(II) complexes with 4-azidopyridine as co-ligandcitations
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article
Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M = Ni, Co, Cd) complexes.
Abstract
Three 1-dimensional azido-bridged transition metal (II) complexes, [Ni2(4-azpy)4(μ1,1-N3)2(μ1,3-N3)2]n (1), [Co2(4-azpy)4(μ1,1-N3)2(μ1,3-N3)2]n (2), and [Cd2(4-azpy)4(μ1,1-N3)2(μ1,3-N3)2]n (3), (4-azpy = 4-azidopyridine) were synthesized and characterized by UV-visible, IR spectroscopy and by single crystal diffraction.The three iso-structural complexes exhibit distorted octahedral geometry around the metal(II) centers, terminal 4-azidopyridine ligands in trans-dispositions and alternating doubly bridged EO- and doubly bridged EE-azido ligands giving rise to polymeric 1-dimensional systems.The asym. nature of the azide groups is increasing from EE- via EO- to covalent bonded N3-group in the 4-azidopyridine ligand.The magnetic properties of complexes 1 and 2 are reported. [on SciFinder(R)]