| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mautner, Franz A.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2023Dinuclear doubly bridged phenoxido copper(II) complexes as efficient anticancer agentscitations
- 2023Structure and magnetic characterization of some bicompartmental [N6O2] divalent metal(ii) complexes using bis(phenolato) ligands bearing two pendant bis(pyridyl) amine arms
- 2023Magnetostructural Properties of Some Doubly-Bridged Phenoxido Copper(II) Complexescitations
- 2023Copper(II) and zinc(II) complexes bridged by benzenoid aromatic oxocarbon and dicarboxylate dianionscitations
- 2021Synthesis, crystal structures, spectral, magnetic and thermal properties of 1-D polymeric dicyanamido-metal(II) complexescitations
- 2021Identification of potent anticancer copper(ii) complexes containing tripodal bis[2-ethyl-di(3,5-dialkyl-1H-pyrazol-1-yl)]amine moietycitations
- 2021Syntheses, structural characterization, and thermal behaviour of metal complexes with 3-aminopyridine as co-ligandscitations
- 2019Thiocyanato-metal(II) and azido-cobalt(III) complexes with hydroxymethylpyridinescitations
- 2017Synthesis, structural characterization and magnetic properties of polymeric azido Mn(II) complexes based on methyl-pyridine-N-oxide co-ligandscitations
- 2017Pyridyl and triazole ligands directing the assembling of zinc(II) into coordination polymers with different dimensionality through azides.citations
- 2016Metal(II) complexes of compartmental polynuclear schiff bases containing phenolate and alkoxy groups.citations
- 2016Synthesis, characterization and luminescence properties of zinc(II) and cadmium(II) pseudohalide complexes derived from quinoline-N-oxide.citations
- 2015Influence of co-ligands in synthesis, photoluminescence behavior and catalytic activities of zinc complexes of 2-((E)-((pyridin-2-yl)methylimino)methyl)phenol.citations
- 2015Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes.citations
- 2015Synthesis, characterization and luminescence properties of zinc(II) complexes of pseudohalides and nitrite derived from 4-azidopyridinecitations
- 2015Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M = Ni, Co, Cd) complexes.citations
- 2015Five-coordinate metal(II) complexes based pyrazolyl ligands.citations
- 2015Synthesis and characterization of five new thiocyanato- and cyanato-metal(II) complexes with 4-azidopyridine as co-ligandcitations
Places of action
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article
Influence of co-ligands in synthesis, photoluminescence behavior and catalytic activities of zinc complexes of 2-((E)-((pyridin-2-yl)methylimino)methyl)phenol.
Abstract
Four new zinc(II) complexes of a tridentate Schiff base ligand 2-((E)-((pyridin-2-yl)methylimino)methyl)phenol (HL), namely [Zn2L2Cl2] (1); [Zn2L2Br2] (2); [ZnL(SCN)(MeOH)] (3) and [Zn2L(OAc)3(MeOH)] (4) were synthesized with the view to study the role of co-ligands in controlling the structural diversity, photoluminescence property and catalytic activities.The complexes were characterized through common physicochem. techniques as well as by x-ray single crystal structural anal.All of them display interesting co-ligands mediated photoluminescence property the origin of which may be attributed due to ligand to metal charge transfer (LMCT) and the order of photoluminescence efficiency is 3 > 4 > 1-2.Catecholase and phosphatase activities of the complexes were studied in DMF medium using 3,5-di-tert-butylcatechol (3,5-DTBC) and 4-nitrophenylphosphate as substrates, resp.Co-ligands have prominent role on phosphatase activity of the complexes where the order of activity in terms of kcat value is 4 > 1 > 2 > 3.Only complex 4 is active in catalyzing the aerobic oxidn. of 3,5-DTBC.The presence of readily labile solvent mol. in one of the zinc centers of complex 4 perhaps takes the key role for initiating substrate-Zn interaction and thereby the activity.Radical pathway is the probable reason behind the catecholate activity as is evident from EPR study.Solid state thermal anal. suggests that ZnO is the thermally stable end product for complexes 1, 2 and 4, whereas it is ZnS in case of complex 3. [on SciFinder(R)]