| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Doert, Thomas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (41/41 displayed)
- 2024Comparison of local structure of CrCl3 bulk and nanocrystals above and below the structural phase transition
- 2023Nano-scale new Heusler compounds NiRh2Sb and CuRh2Sbcitations
- 2023Spontaneous polarization and pyroelectric coefficient of lithium niobate and lithium tantalate determined from crystal structure datacitations
- 2023In situ Investigations of the Formation Mechanism of Metastable γ ‐BiPd Nanoparticles in Polyol Reductions
- 2023Unconventional Spin State Driven Spontaneous Magnetization in a Praseodymium Iron Antimonidecitations
- 2022$mathrm{In}$ $mathrm{situ}$ investigation of the formation mechanism of $α$-Bi$_2$Rh nanoparticles in polyol reductionscitations
- 2022In situ investigation of the formation mechanism of α-Bi2Rh nanoparticles in polyol reductionscitations
- 2022Combined experimental and theoretical study of hydrostatic (He-gas) pressure effects in α-RuCl3citations
- 2021Freestanding Nanolayers of a Wide-Gap Topological Insulator through Liquid-Phase Exfoliationcitations
- 2021Freestanding Nanolayers of a Wide-Gap Topological Insulator through Liquid-Phase Exfoliation
- 2021Formation of Bi2Ir nanoparticles in a microwave-assisted polyol process revealing the suboxide Bi4Ir2Ocitations
- 2021Freestanding few-layer sheets of a dual topological insulatorcitations
- 2021Low Temperature Activation of Tellurium and Resource-Efficient Synthesis of AuTe2 and Ag2Te in Ionic Liquidscitations
- 2021Hydrothermal Synthesis, Crystal Structure, and Magnetism of Na2[Ir(OH)6] and its Dehydration to Na2IrO3citations
- 2021Tunable Potassium Ion Conductivity and Magnetism in Substituted Layered Ferratescitations
- 2021Atypical transport for GdTe1.8 upon substitution with Se: Strong electron-phonon coupling in polaronic conduction
- 2021Formation of Bi$_2$Ir nanoparticles in a microwave-assisted polyol process revealing the suboxide Bi$_4$Ir$_2$Ocitations
- 2021Ba3[Rh(OH)6]2 ⋅ H2O – a Precursor to Barium Oxorhodates with One-dimensional Hydrogen Bonding Systemscitations
- 2020Synthesis of $(Li_{2}Fe_{1–y}Mn_{y})SO$ Antiperovskites with Comprehensive Investigations of $(Li_{2}Fe_{0.5}Mn_{0.5})SO$ as Cathode in Li-ion Batteriescitations
- 2020Hydroflux syntheses and crystal structures of hydrogarnets Ba3[RE(OH)6]2(RE = Sc, Y, Ho-Lu)citations
- 2020The Hydrogarnets Sr3[RE(OH)6]2 (RE = Sc, Y, Ho – Lu): Syntheses, Crystal Structures, and their Thermal Decomposition to Ternary Rare-Earth Metal Oxidescitations
- 2020CaNa[Cr(OH)6] – A Layered Hydroxochromate(III) with Ordered Brucite Structure and its Thermal Decompositioncitations
- 2020The Weak 3D Topological Insulator Bi12Rh3Sn3I9
- 2019Syntheses, Crystal Structures and Physical Properties of Chromium and Rhodium Hydrogarnets Ca 3 [Cr(OH) 6 ] 2 , Sr 3 [Cr(OH) 6 ] 2 and Sr 3 [Rh(OH) 6 ] 2citations
- 2019Mechanism of Bi−Ni Phase Formation in a Microwave-Assisted Polyol Process
- 2018The Intermetalloid Cluster Cation (CuBi8)3+citations
- 2017Optimized Synthesis of the Bismuth Subiodides BmI4 (m = 4, 14, 16, 18) and the Electronic Properties of Bi14I4 and Bi18I4citations
- 2016Jeff Description of the Honeycomb Mott Insulator α-RuCl3citations
- 2016Downscaling Effect on the Superconductivity of Pd3Bi2X2 (X = S or Se) Nanoparticles Prepared by Microwave-Assisted Polyol Synthesiscitations
- 2016Resource-Efficient High-Yield Ionothermal Synthesis of Microcrystalline Cu3-xPcitations
- 2014Synthesis, crystal structures, spectroscopic and electrochemical studies on Cu(II) and Ni(II) complexes with compartmental nitrogen-oxygen mixed donor ligandscitations
- 2014Single-crystal X-ray diffraction investigation of the reversible order-disorder phase transition in iron-deficient TlFe2-xSe2citations
- 2013Tetragonal to orthorhombic phase transition of GdFeAsO studied by single-crystal X-ray diffractioncitations
- 2012Ternary lanthanum sulfide selenides α-LaS2-xSex (0<x<2) with mixed dichalcogenide anions X22- (X=S, Se)citations
- 2011Proliferation, differentiation and gene expression of osteoblasts in boron-containing associated with dexamethasone deliver from mesoporous bioactive glass scaffoldscitations
- 2011Bioactive SrO-SiO<sub>2</sub> glass with well-ordered mesopores: Characterization, physiochemistry and biological propertiescitations
- 2011High-pressure synthesis of rare-earth metal disulfides and diselenides LnX2 (Ln = Sm, Gd, Tb, Dy, Ho, Er and Tm; X = S, Se)citations
- 2005Incommensurately modulated CeSi1.82citations
- 2004Structure-Property Relations and Diffusion Pathways of the Silver Ion Conductor Ag5Te2Clcitations
- 2004Magnetic, electrical resistivity, heat-capacity, and thermopower anomalies in CeCuAs2citations
- 2003Enhanced electrical resistivity before Néel order in the metals RCuAs2 (R = Sm, Gd, Tb, and Dy)citations
Places of action
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article
Synthesis, crystal structures, spectroscopic and electrochemical studies on Cu(II) and Ni(II) complexes with compartmental nitrogen-oxygen mixed donor ligands
Abstract
<p>The synthesis and characterization of two new N<sub>2</sub>O<sub>4</sub> donor type ligands, 2-{[(2-{3-[2-({[(2-hydroxyphenyl)methylidene]amino}methyl) phenoxy]propoxy}benzyl)imino]methyl}phenol (H<sub>2</sub>L1) and 2-[({2-[3-(2-{[(2-hydroxybenzyl)amino]methyl}phenoxy)propoxy]benzyl}amino) methyl]phenol (H<sub>2</sub>L2), and their metal complexes with Cu(II) and Ni(II) metal ions are reported. The ligands and complexes have been characterized by <sup>1</sup>H NMR, FT-IR, UV-Vis absorption spectroscopy, single-crystal X-ray diffraction, CHN elemental analysis and cyclic voltammetry (CV). The redox behavior of the two complexes has been studied by CV. Copper and nickel complexes of Schiff base (H<sub>2</sub>L1) and reduced Schiff base (H<sub>2</sub>L2) showed different behaviors because the structure of the complexes depends of the ligand. The complex [Cu<sub>2</sub>L1 <sub>2</sub>]·2CH<sub>3</sub>OH (1) is dinuclear with the two metal centers bridged exclusively by the ligands, consisting of two distorted square planar CuN<sub>2</sub>O<sub>2</sub> chromophors with large intermetallic separation (8.879 Å). Complex [Ni<sub>4</sub>L2<sub>2</sub>(CH <sub>3</sub>COO)<sub>4</sub>]·4CH<sub>3</sub>OH (2) consists of tetranuclear Ni<sub>4</sub> unit of two symmetry related hexacoordinated nickel atoms having distorted octahedral NiN<sub>2</sub>O<sub>4</sub> and NiO <sub>6</sub> environments, and contains two types of acetate coordination modes, namely, bridging bidentate (μ<sub>2</sub>-η<sup>1</sup>, η<sup>1</sup>), and asymmetric chelating bridging (μ<sub>2</sub>- η<sup>2</sup>, η<sup>1</sup>).</p>