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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Saha, Rajat
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivitycitations
- 2024A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)2]n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 Kcitations
- 2024Simultaneous hydroxido-, nitrato-, and phenoxido-bridged binuclear copper Schiff base complex for green catalytic click chemistry: Synthesis, structure, Hirshfeld surface analysis, theoretical study and photoluminescence spectracitations
- 2024Carbazole diester strapped calix[4]pyrrole: Synthesis, anion binding and self-assembly based on ion pair recognitioncitations
- 2024Rhodamine hydrazide-linked naphthalimide derivative: Selective naked eye detection of Cu2+, S2− and understanding the therapeutic potential of the copper complex as an anti-cervical cancer agentcitations
- 2023Electrocatalytic Water Oxidation by Hydrolytically Stable Metal‐Organic Frameworks at Both Neutral and Alkaline Medium: Inverse Relation of Dimensionality with Catalytic Activitycitations
- 2023Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivitycitations
- 2023A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)2]n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 Kcitations
- 2022Simultaneous presence of mono- and bi-cationic bipyridyls within a metal-organic supramolecular host: crystal structure, spectral and Hirshfeld surface analysiscitations
- 2022Solvent‐ and Substrate‐Induced Chiroptical Inversion in Amphiphilic, Biocompatible Glycoconjugate Supramolecules: Shape‐Persistent Gelation, Self‐Healing, and Antibacterial Activitycitations
- 2021Photo-responsive Schottky Diode Behavior of a Donor-Acceptor Co-crystal with Violet Blue Light Emissioncitations
- 2014Synthesis, characterization, X-ray crystallography and antimicrobial activities of new Co(III) and Cu(II) complexes with a pyrazole based Schiff base ligandcitations
Places of action
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article
Synthesis, characterization, X-ray crystallography and antimicrobial activities of new Co(III) and Cu(II) complexes with a pyrazole based Schiff base ligand
Abstract
A new pyrazole based 'NNS' tridentate ligand, 5-methylpyrazole-3yl-N-(2'-methylthiophenyl)methyleneimine (MPzOATA), has been synthesized and characterized by elemental analyses, mass, IR and NMR spectroscopy. The versatile coordination mode of the ligand has been established with the synthesis of two metal-organic complexes with different metal ions, Co(III) (complex I) and Cu(II) (complex II). These metal-organic complexes have been characterized by single crystal X-ray structure analyses, along with several spectral techniques. Structural analyses of both the monomeric complexes reveal that complex I crystallized in the monoclinic C2/c space group, while complex II crystallized in the orthorhombic Pbca (#61) space group. In complex I, the Co(III) centre shows a six coordinate octahedral geometry, while in complex II, the Cu(II) centre shows a five coordinate square pyramidal geometry. The reported ligand and the metal ion complexes have been screened for their in vitro antimicrobial activity against some pathogenic bacteria. (C) 2013 Elsevier Ltd. All rights reserved.