• Pillet, Sébastien
• Houille, Sylvie
• Setifi, Fatima
• Charles, Catherine
• Thétiot, Franck
• Gómez-García, Carlos J.
• Triki, Smail

Abstract

New iron(II) coordination polymeric neutral chain of formula [Fe(abpt)2(μ-M(CN)4)], with M = PtII (1), NiII (2) and abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole, have been synthesized and characterized by infrared spectroscopy, X-ray diffraction and magnetic measurements. The two compounds are isostructural as deduced from a Rietveld analysis of X-ray powder diffraction data of 2 simulated from the single crystal structure of 1. The crystal packing of 1 is formed by regular chains running along the crystallographic [−1 0 1] direction where the planar [Pt(CN)4]2− anion acts as a μ2-bridging ligand via two nitrogen atoms of two different trans cyano groups, while the two abpt molecules act as chelating ligands. Along the neutral chains, the Fe⋯Pt distances are imposed by the cyano groups of the [Pt(CN)4]2− moiety (5.027 and 5.022 Å at 294 and 150 K, respectively), leading to Fe⋯Fe intrachain distances of 10.055 and 10.045 Å at 294 and 150 K, respectively. The thermal dependence of the product of the molar magnetic susceptibility times the temperature (χmT) for compound 1 shows a constant value close to 0.2 emu K mol−1 in the temperature range 10–300 K in the cooling and warming scans. Above 300 K, compound 1 shows a SCO transition from the LS to the HS configuration although the transition is not fully achieved at 400 K.

Topics

• impedance spectroscopy
• compound
• polymer
• single crystal
• x-ray diffraction
• Nitrogen
• iron
• susceptibility
• laser sintering
• infrared spectroscopy