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article
Synthesis and characterization of adducts of bis(O,O '-ditolyl/dibenzyl dithiophosphato)cobalt(II) with pyridine: Crystal structures of [Co{S2P(OC6H4Me-p)(2)}(2)(C5H5N)(2)] and [Co{S2P(OC6H4Me-p)(2)}(2)(NH3)]
Abstract
Bis(O,O'-ditolyl/dibenzyl dithiophosphato)cobalt(II) complexes with pyridine ligands of the type [Co{S2P(OR)(2)}(2)(C5H5N)(2)] (R = o-, m-, p-C6H4Me, CH2Ph) have been synthesized by the reaction of CoCl2(C5H5N)(2) and the corresponding ammonium salt of O,O'-ditolyl/dibenzyl dithiophosphate in methanol. These newly synthesized adducts were characterized by elemental analysis, IR, UV-Vis spectroscopy, magnetic susceptibility measurements and single crystal X-ray diffraction. These structures confirm that in the pyridine complex the geometry around the cobalt metal centre is distorted octahedral, and in the amine complex it is distorted trigonal bipyramidal.