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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Feron, Krishna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Deducing transport properties of mobile vacancies from perovskite solar cell characteristicscitations
- 2020Deducing transport properties of mobile vacancies from perovskite solar cell characteristicscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2019Building intermixed donor-acceptor architectures for water-processable organic photovoltaicscitations
- 2018Engineering Two-Phase and Three-Phase Microstructures from Water-Based Dispersions of Nanoparticles for Eco-Friendly Polymer Solar Cell Applicationscitations
- 2018Engineering Two-Phase and Three-Phase Microstructures from Water-Based Dispersions of Nanoparticles for Eco-Friendly Polymer Solar Cell Applications
- 2018Vinylene and benzo[c][1,2,5]thiadiazole: effect of the pi-spacer unit on the properties of bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing polymers for n-channel organic field-effect transistorscitations
- 2018Molecular engineering using an anthanthrone dye for low-cost hole transport materials: A strategy for dopant-free, high-efficiency, and stable perovskite solar cellscitations
- 2018Tunable Crystallization and Nucleation of Planar CH3NH3PbI3 through Solvent-Modified Interdiffusioncitations
- 2017Energy level engineering in ternary organic solar cells: evaluating exciton dissociation at organic semiconductor interfacescitations
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article
Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cells
Abstract
<p>In this work, a fluorinated pyrene-based organic semiconductor (L-F) has been designed and synthesized starting from a low-cost pyrene core functionalized with triphenilamine substituents at 1,3,6,8 positions (L-H), obtained via Suzuki coupling reactions. Its performance when used as green emitter in organic light emitting diodes (OLEDs) or as dopant-free hole-transporting material (HTM) in halide perovskite solar cells (PSCs) is higher than that of the L-H counterpart, in spite of its lower bulk hole-mobility (7.0 × 10<sup>−6</sup> cm<sup>2</sup>/V) to L-H (1.9 × 10<sup>−4</sup> cm<sup>2</sup>/V). In fact, the OLED devices based on a L-F active layer showed excellent green emission (brightness and current efficiency were 1759.8 cd/m<sup>2</sup> and 3.7 cd/A, respectively) at a 4.5 V turn-on voltage. When the molecules were employed as a dopant-free HTM in PSCs, L-F led to a power conversion efficiency (PCE) and open circuit voltage (V<sub>oc</sub>) of 5.9% and 1.07 V, respectively, thus outperforming those of corresponding devices based on L-H (PCE = 5.0% and V<sub>oc</sub> = 0.87 V) under similar experimental conditions (AM 1.5G and 100 mW cm<sup>2</sup>). We attribute the enhancements of L-F-based optoelectronic devices (OLEDs and PSCs) to the observed better quality of the L-F films. The promising performance of L-F indicates that fluorination of small molecules can be an effective strategy to achieve low-cost and high-performing materials for energy harvesting and display-based organic electronic devices.</p>