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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kumar, Abhinav
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Optimization of surface roughness in milling of EN 24 steel with WC-Coated inserts using response surface methodology: analysis using surface integrity microstructural characterizationscitations
- 2024Biosurfactants in biocorrosion and corrosion mitigation of metals: An overviewcitations
- 2023The Microstructure and Properties of Ni-Si-La2O3 Coatings Deposited on 304 Stainless Steel by Microwave Claddingcitations
- 2023Prediction and simulation of mechanical properties of borophene-reinforced epoxy nanocomposites using molecular dynamics and FEAcitations
- 2023Effect of Pulsation in Microstructure and Mechanical Properties of Titanium Alloy-Annealed Welded Joints at Different Temperaturescitations
- 2022Diaminopyridine Hg(II)-based 1D supramolecular polymercitations
- 2022Ferrocene Appended Asymmetric Sensitizers with Azine Spacers with phenolic/nitro anchors for Dye-Sensitized Solar Cellscitations
- 2020A new 1D coordination polymer of triphenyl lead hydrosulfide: Synthesis and insights into crystal architecture and Hirshfeld surface analysescitations
- 2016Transition metal ferrocenyl dithiocarbamates functionalized dye-sensitized solar cells with hydroxy as an anchoring groupcitations
Places of action
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article
Transition metal ferrocenyl dithiocarbamates functionalized dye-sensitized solar cells with hydroxy as an anchoring group
Abstract
<p>Three new transition-metal dithiocarbamates involving ferrocene (Fc), namely [Co(FcCH<sub>2</sub>EtOHdtc)<sub>3</sub>] (Co), [M(FcCH<sub>2</sub>EtOHdtc)<sub>2</sub>] M = Ni (Ni), Cu (Cu) (EtOHdtc = N-ethanol dithiocarbamate), have been synthesized and characterized by microanalyses, FTIR, <sup>1</sup>H and <sup>13</sup>C NMR spectroscopies and single crystal X-ray diffraction technique. The peak broadening in the <sup>1</sup>H spectrum of the copper complex indicates the paramagnetic behavior of this compound. The observed single quasi-reversible cyclic voltammograms for the complexes indicate the stabilization of a metal center (except copper) other than Fe in their characteristic oxidation state. These complexes have been used as photo-sensitizer in dye-sensitized solar cells which indicates that Co displays the best photosensitization property with an overall conversion efficiency of 3.25 ± 0.04%. The low cell efficiency of Ni and Cu complexes may be due to slow regeneration of the dye by iodine/iodide redox couple followed by charge injection into TiO<sub>2</sub>.</p>