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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cordier, Stéphane
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (48/48 displayed)
- 2024Effect of an Aromatic Sulfonate Ligand on the Photovoltaic Performance of Molybdenum Cluster-Sensitized Solar Cellscitations
- 2023Flexible and Transparent Luminescent Cellulose-Transition Metal Cluster Compositescitations
- 2023Enhanced NH3 Sensing Performance of Mo Cluster-MoS2 Nanocomposite Thin Films via the Sulfurization of Mo6 Cluster Iodides Precursorcitations
- 2023From Solid-State Cluster Compounds to Functional PMMA-Based Composites with UV and NIR Blocking Properties, and Tuned Hues
- 2022High performance {Nb5TaX12}@PVP (X = Cl, Br) cluster-based nanocomposites coatings for solar glazing applicationscitations
- 2022A review on functional nanoarchitectonics nanocomposites based on octahedral metal atom clusters (Nb-6, Mo-6, Ta-6, W-6, Re-6): inorganic 0D and 2D powders and filmscitations
- 2022Surface Plasmon Tunability of Core-Shell Au@Mo(6) Nanoparticles by Shell Thickness Modificationcitations
- 2022Controlling the Deposition Process of Nanoarchitectonic Nanocomposites Based on {Nb(6-x)Ta(x)X(i)(12)}(n+) Octahedral Cluster-Based Building Blocks (X(i) = Cl, Br; 0 ≤ x ≤ 6, n = 2, 3, 4) for UV-NIR Blockers Coating Applicationscitations
- 2022Reentrant structural and optical properties of organic-inorganic hybrid metal cluster compound ((n-C4H9)(4)N)(2)[(Mo6Br8Br6a)-Br-i]citations
- 2022Nanoarchitectonics of Glass Coatings for Near-Infrared Shielding: From Solid-State Cluster-Based Niobium Chlorides to the Shaping of Nanocomposite Filmscitations
- 2022Reentrant structural and optical properties of organic-inorganic hybrid metal cluster compound ((n-C4H9)(4)N)(2)[(Mo6Bri8Br6a)]citations
- 2022Joint Venture of Metal Cluster and Amphiphilic Cationic Minidendron Resulting in Near Infrared Emissive Lamellar Ionic Liquid Crystalscitations
- 2022Light-dependent ionic-electronic conduction in an amorphous octahedral molybdenum cluster thin filmcitations
- 2021Poly(dimethylsiloxane) functionalized with complementary organic and inorganic emitters for the design of white emissive waveguidescitations
- 2021Expanding the Toolbox of Octahedral Molybdenum Clusters and Nanocomposites Made Thereof: Evidence of Two-Photon Absorption Induced NIR Emission and Singlet Oxygen Productioncitations
- 2021Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradationcitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2020Zn-Al layered double hydroxide-based nanocomposite functionalized with an octahedral molybdenum cluster exhibiting prominent photoactive and oxidation propertiescitations
- 2020Time-Resolved In Situ Neutron Diffraction Study of Cu22Fe8Ge4S32 Germanite: A Guide for the Synthesis of Complex Chalcogenidescitations
- 2020Preparation and characterization of hollow silica nanocomposite functionalized with UV absorbable molybdenum clustercitations
- 2020Zn-Al Layered Double Hydroxide Film Functionalized by a Luminescent Octahedral Molybdenum Cluster: Ultraviolet-Visible Photoconductivity Responsecitations
- 2020Switchable Two-Dimensional Waveguiding Abilities of Luminescent Hybrid Nanocomposites for Active Solar Concentratorscitations
- 2019Transparent functional nanocomposite films based on octahedral metal clusters synthesis by electrophoretic deposition process and characterizationcitations
- 2019ITO@SiO2 and ITO@{M6Br12}@SiO2 (M = Nb, Ta) nanocomposite films for ultraviolet-near infrared shieldingcitations
- 2018Elastic softness of hybrid lead halide perovskites
- 2018Elastic softness of hybrid lead halide perovskitescitations
- 2018Lord of The Crowns A New Precious in the Kingdom of Clustomesogenscitations
- 2018Low-frequency Raman spectroscopy and elastic softness of hybrid lead halide perovskites
- 2018Low dimensional solids based on Mo-6 cluster cyanides and Mn2+, Mn3+ or Cd2+ metal ions crystal chemistry, magnetic and optical propertiescitations
- 2017Designing a Thermoelectric Copper-Rich Sulfide from a Natural Mineral: Synthetic Germanite Cu22Fe8Ge4S32citations
- 2017High temperature neutron powder diffraction study of the Cu12Sb4S13 and Cu4Sn7S16 phasescitations
- 2017Transparent tantalum cluster-based UV and IR blocking electrochromic devicescitations
- 2017Simulation of crystal and electronic structures of octahedral molybdenum cluster complex compound Cs-2[Mo6Cl14] using various DFT functionalscitations
- 2016Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blockscitations
- 2016Time-gated luminescence bioimaging with new luminescent nanocolloids based on [Mo6I8(C2F5COO)(6)](2-) metal atom clusterscitations
- 2016Efficient active waveguiding properties of Mo6 nano-cluster-doped polymer nanotubes
- 2016Plastic crystal behavior, tight-binding modelling and low energy phonon spectroscopy in hybrid perovskites crystals
- 2016Inorganic Molybdenum Clusters as Light-Harvester in All Inorganic Solar Cells: A Proof of Conceptcitations
- 2016Facile design of red-emitting waveguides using hybrid nanocomposites made of inorganic clusters dispersed in SU8 photoresist hostcitations
- 2015Surface immobilization of Mo6I8 octahedral cluster cores on functionalized amorphous carbon using a pyridine complexation strategycitations
- 2015Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensingcitations
- 2014Deep red luminescent hybrid copolymer materials with high transition metal cluster contentcitations
- 2013One-pot synthesis of gold nanoparticle/molybdenum cluster/graphene oxide nanocomposite and its photocatalytic activitycitations
- 2013Color control in coaxial two-luminophore nanowires.citations
- 2010Fine tuning of emission through the engineering of colloidal crystalscitations
- 2008When “metal atom clusters” meet ZnO Nanocrystals: A ((n-C4H9)4N)2Mo6Br14@ZnO hybrid.citations
- 2006Mn5Si3-type host-interstitial boron rare-earth metal silicide compounds RE5Si3: Crystal structures, physical properties and theoretical considerationscitations
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article
Facile design of red-emitting waveguides using hybrid nanocomposites made of inorganic clusters dispersed in SU8 photoresist host
Abstract
International audience ; Integration of stable emissive entities into organic waveguide with minimum scattering is essential to design efficient optically active devices. Here we present a new class of doped nanocomposite waveguides exploiting 1-nm diameter metallic cluster-based building blocks as red-NIR luminescent dyes embedded in a SU8 polymeric matrix, a reference photoresist for organic photonics. These building blocks are [Mo6Ii8(OOCC2F5)a6]2− cluster anionic units with unique chemical and physical features well suited for optical nanocomposites such as a ligand-promoted dispersibility, a large Stokes shift with a broad absorption window and an emission window in the range 600–900 nm. A whole investigation of the nanocomposite has been first performed. Optical characterizations of Cs2[Mo6Ii8(OOCCnF2n+1)a6]@SU8 nanocomposites thin film and waveguiding structures show their relevance as active layers in integrated structures with a significant increase of the refractive index of 3 × 10−2 when the cluster concentration increases up to 4 wt%, while keeping high values for the transmitted power, as shown for different waveguide dimensions and clusters concentrations. The efficiency of photoluminescence propagation is investigated as a function of clusters concentration in the excitation area for several waveguides dimensions. Attenuation coefficient ranges between 5 and 18 dB/cm, values of the same order of magnitude as those obtained in polymeric waveguide doped with QDs or organic dyes. This original, stable and efficient nanocomposite is promising for downscaling complex nanosources and active waveguides in the visible and NIR range.