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Adegoke, Oluwasesan
University of Dundee
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Insight into the electrochemical performance of heavy metal-free quantum dots in different buffered ferricyanide/ferrocyanide redox systemscitations
- 2024Molecularly Imprinted Viral Protein Integrated Zn−Cu−In−Se−P Quantum Dots Superlattice for Quantitative Ratiometric Electrochemical Detection of SARS-CoV‑2 Spike Protein in Salivacitations
- 2024An organic-inorganic polyacrylamide-based surface imprinted quantum dots for the impedimetric and voltammetric detection of diazepam in saliva with smartphone readoutcitations
- 2024Molecularly Imprinted Viral Protein Integrated Zn-Cu-In-Se-P Quantum Dots Superlattice for Quantitative Ratiometric Electrochemical Detection of SARS-COV-2 Spike Protein in Salivacitations
- 2024Molecularly imprinted viral protein integrated Zn-Cu-In-Se-P quantum dots superlattice for quantitative ratiometric electrochemical detection of SARS-CoV-2 spike protein in salivacitations
- 2024Heavy metal-free MnInPSeS alloyed quantum dots-molecularly imprinted polymer as an electrochemical nanosensor for the detection of the synthetic cathinone, 3,4-methylenedioxypyrovaleronecitations
- 2024Heavy metal-free MnInPSeS alloyed quantum dots-molecularly imprinted polymer as an electrochemical nanosensor for the detection of the synthetic cathinone, 3,4-methylenedioxypyrovaleronecitations
- 2023Cadmium-free silica-encapsulated molecularly imprinted AuZnCeSeS quantum dots nanocomposite as an ultrasensitive fluorescence nanosensor for methamphetamine detectioncitations
- 2023Blue-emitting SiO 2 -coated Si-doped ZnSeS quantum dots conjugated aptamer-molecular beacon as an electrochemical and metal-enhanced fluorescence biosensor for SARS-CoV-2 spike proteincitations
- 2023Blue-emitting SiO2-coated Si-doped ZnSeS quantum dots conjugated aptamer-molecular beacon as an electrochemical and metal-enhanced fluorescence biosensor for SARS-CoV-2 spike proteincitations
- 2022Thiolated gamma-cyclodextrin-polymer-functionalized CeFe3O4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxidecitations
- 2022Alloyed AuFeZnSe quantum dots@gold nanorod nanocomposite as an ultrasensitive and selective plasmon-amplified fluorescence OFF-ON aptasensor for arsenic (III)citations
- 2022Alloyed AuFeZnSe quantum dots@gold nanorod nanocomposite as an ultrasensitive and selective plasmon-amplified fluorescence OFF-ON aptasensor for arsenic (III)citations
- 2022Thiolated gamma-cyclodextrin-polymer-functionalized CeFe 3 O 4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxidecitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2021Organometallic synthesis, structural and optical properties of CdSe quantum dots passivated with ternary AgZnS alloyed shellcitations
- 2021Polymeric-coated Fe-doped ceria/gold hybrid nanocomposite as an aptasensor for the catalytic enhanced colorimetric detection of 2,4-dinitrophenolcitations
- 2021Polymeric-coated Fe-doped ceria/gold hybrid nanocomposite as an aptasensor for the catalytic enhanced colorimetric detection of 2,4-dinitrophenolcitations
- 2020Aptamer-based cocaine assay using a nanohybrid composed of ZnS/Ag2Se quantum dots, graphene oxide and gold nanoparticles as a fluorescent probecitations
- 2020Fluorometric virus detection platform using quantum dots-gold nanocomposites optimizing the linker length variationcitations
- 2020Fluorometric virus detection platform using quantum dots-gold nanocomposites optimizing the linker length variationcitations
- 2019Passivating effect of ternary alloyed AgZnSe shell layer on the structural and luminescent properties of CdS quantum dotscitations
- 2019Multi-shaped cationic gold nanoparticle-L-cysteine-ZnSeS quantum dots hybrid nanozyme as an intrinsic peroxidase mimic for the rapid colorimetric detection of cocainecitations
- 2019Multi-shaped cationic gold nanoparticle-L-cysteine-ZnSeS quantum dots hybrid nanozyme as an intrinsic peroxidase mimic for the rapid colorimetric detection of cocainecitations
- 2018Single-step detection of norovirus tuning localized surface plasmon resonance-induced optical signal between gold nanoparticles and quantum dotscitations
- 2017Bright luminescent optically engineered core/alloyed shell quantum dotscitations
- 2017Alloyed quaternary/binary core/shell quantum dot-graphene oxide nanocomposite:Preparation, characterization and application as a fluorescence “switch ON” probe for environmental pollutantscitations
- 2017Alloyed quaternary/binary core/shell quantum dot-graphene oxide nanocompositecitations
- 2017Bright luminescent optically engineered core/alloyed shell quantum dots: an ultrasensitive signal transducer for dengue virus RNA via localized surface plasmon resonance-induced hairpin hybridizationcitations
- 2016Gradient band gap engineered alloyed quaternary/ternary CdZnSeS/ZnSeS quantum dotscitations
- 2016L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detectioncitations
- 2016Size-confined fixed-composition and composition-dependent engineered band gap alloying induces different internal structures in L-cysteine-capped alloyed quaternary CdZnTeS quantum dotscitations
- 2016Fluorescence properties of alloyed ZnSeS quantum dots overcoated with ZnTe and ZnTe/ZnS shellscitations
- 2015Optical properties of water-soluble l-cysteine-capped alloyed CdSeS quantum dot passivated with ZnSeTe and ZnSeTe/ZnS shellscitations
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article
Optical properties of water-soluble l-cysteine-capped alloyed CdSeS quantum dot passivated with ZnSeTe and ZnSeTe/ZnS shells
Abstract
Alloyed quantum dots (QDs) passivated with shell materials have valuable optical characteristics suitable for a wide array of applications. In this work, alloyed ternary CdSeS QDs passivated with ZnSeTe and ZnSeTe/ZnS shells have been synthesized via a hot-injection method and a ligand exchange reaction employing l-cysteine as a thiol ligand has been used to obtain these water-soluble nanocrystals for the first time. The photoluminescence (PL) quantum yield (QY) of alloyed l-cysteine-capped CdSeS was 71.2% but decreased significantly to 5.2% upon passivation with a ZnSeTe shell. The red shift in PL emission of the CdSeS/ZnSeTe QDs was attributed to be strain-induced whilst a lattice-induced process likely created defect states in the core/shell interface hence contributing to the decline in the PL QY. Nonetheless, the fluorescence stability of CdSeS/ZnSeTe QDs in aqueous solution was unperturbed. Further passivation with a ZnS shell (CdSeS/ZnSeTe/ZnS) improved the PL QY to a value of 58.7% and thus indicates that the defect state in the QDs core/shell/shell structure was reduced. PL lifetime exciton measurements indicated that the rates of decay of the QDs influenced their photophysical properties.