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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lasgorceix, Marie
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 20233D technology and antibacterial post-treatments: the process for the future manufacturing of bone substitutes?
- 2023Mg2+, Sr2+, Ag+, and Cu2+ co‐doped β‐tricalcium phosphate: Improved thermal stability and mechanical and biological propertiescitations
- 2023Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applicationscitations
- 2023Synthesis and Direct Ink Writing of doped β-tricalcium phosphate bioceramics for bone repair applications
- 2023Shaping of complex ceramic parts by several additive manufacturing processes
- 2023Surface structuring of β-TCP and transition to α-TCP induced by femtosecond laser processingcitations
- 2023Macroporous biphasic calcium phosphate materials for bone substitute applications
- 2023Cold Sintering Process for developing hydroxyapatite ceramic and polymer composite
- 2023Cold Sintering Process for developing hydroxyapatite ceramic and polymer composite
- 20233D printing of doped β-tricalcium phosphate bioceramics using robocasting
- 2023Combination of indirect stereolithography and gel casting methods to shape ceramic dental crowns
- 2022Binder jetting process with ceramic powders ; Binder jetting process with ceramic powders: Influence of powder properties and printing parameterscitations
- 2022Shaping of complex ceramic parts using stereolithography and gel casting
- 2022Manufacturing methods of bioceramic scaffolds
- 2022Shaping of ceramics by hybrid binder jetting
- 2022Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applicationscitations
- 2022Young Ceramists in the Spotlight
- 2022Shaping of ceramic by binder jetting
- 2022Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
- 2022Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
- 2022Post-infiltration to improve the density of binder jetting ceramic partscitations
- 2021Fabrication of higher thermal stability doped β-tricalcium phosphate bioceramics by robocasting
- 2021Influence of dopants on thermal stability and densification of β-tricalcium phosphate powderscitations
- 2021Development of calcium phosphate suspensions suitable for the stereolithography processcitations
- 2021Hybrid additive/subtractive manufacturing system to prepare dense and complicated ceramic parts
- 2020Fabrication of higher thermal stability doped β-tricalcium phosphate bioceramics by robocasting
- 2020Hybrid additive/subtractive manufacturing system to prepare dense and complex shape ceramic parts
- 2019Pre-osteoblast cell colonization of porous silicon substituted hydroxyapatite bioceramics: Influence of microporosity and macropore designcitations
- 2019Micropatterning of beta tricalcium phosphate bioceramic surfaces, by femtosecond laser, for bone marrow stem cells behavior assessmentcitations
- 2016Shaping by microstereolithography and sintering of macro–micro-porous silicon substituted hydroxyapatitecitations
- 2016Quantitative analysis of vascular colonisation and angio-conduction in porous silicon-substituted hydroxyapatite with various pore shapes in a chick chorioallantoic membrane (CAM) modelcitations
- 2014Shaping by microstereolithography and sintering of macro-micro-porous silicated hydroxyapatite ceramics and biological evaluation
Places of action
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article
Influence of dopants on thermal stability and densification of β-tricalcium phosphate powders
Abstract
peer reviewed ; In this work, β-tricalcium phosphate (β-TCP) is doped with Mg2+ and Sr2+ in order to postpone the problematic β-TCP → α-TCP transition occurring from 1125 °C. Indeed, this phase transition occurs with a large lattice expansion during sintering causing microcracks and a reduced shrinkage leading to poor mechanical properties of ceramic parts. The substitution of calcium by cations like Mg2+ and Sr2+ allows to increase the temperature corresponding to β→α-TCP transition and therefore to increase the sintering temperature and achieve higher densification level. Three doping rates for each dopant individually (2.25, 4.50 and 9.00 mol%) and two co-doped compositions (2.00 mol% and 4.00 mol% of Mg2+ and Sr2+ simultaneously) were tested. Thermal and dilatometric analyses were used to evaluate the effects of Mg2+ and Sr2+ doping on the thermal stability of β-TCP. It has been shown that all doping, except the 2.25 mol% Sr-TCP, postpone the β→α transition. These results were confirmed after conventional and microwave sintering. Indeed, X-ray diffraction analyses of sintered pellets showed that the only phase present is β-TCP up to 1300 °C in all compositions except for the 2.25 mol% Sr-TCP with both sintering ways. Moreover, a higher densification rate is observed with the presence of dopants compared to undoped β-TCP according to the microstructures and relative densities close to 100%. Finally, the duration of microwave sintering is almost sixteen times shorter compared to conventional sintering allowing rapid densification with similar final relative densities and microstructures with finer grains.