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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zekonyte, Jurgita
University of Portsmouth
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2022Investigating the Effects of H2O Interaction with Rainscreen Façade ACMs During Fire Exposurecitations
- 2021The effect of temperature on the erosion of polyurethane coatings for wind turbine leading edge protectioncitations
- 2021Wear of 17-4 PH stainless steel patterned surfaces fabricated using selective laser meltingcitations
- 2020Characterization of Nano-Mechanical, Surface and Thermal Properties of Hemp Fiber-Reinforced Polycaprolactone (HF/PCL) Biocompositescitations
- 2020Planning for metal additive manufacturingcitations
- 2020Structure and mechanical properties of Ce-La alloys containing 3- 10 wt. % Lacitations
- 2016Titanate nanotubes for reinforcement of a poly(ethylene oxide)/chitosan polymer matrixcitations
- 2016Titanate nanotubes for reinforcement of a poly(ethylene oxide)/chitosan polymer matrixcitations
- 2016Titanate nanotubes for reinforcement of a poly(ethylene oxide)/chitosan polymer matrixcitations
- 2015Friction force microscopy analysis of self-adaptive W-S-C coatings: nanoscale friction and wearcitations
- 2015Friction force microscopy analysis of self-adaptive W-S-C coatings:nanoscale friction and wearcitations
- 2015Friction force microscopy analysis of self-adaptive W-S-C coatingscitations
- 2014Nanomechanical assessment of human and murine collagen fibrils via atomic force microscopy cantilever-based nanoindentationcitations
- 2014WS2 nanoparticles - potential replacement for ZDDP and friction modifier additivescitations
- 2014Frictional properties of self-adaptive chromium doped tungsten-sulfur-carbon coatings at nanoscalecitations
- 2009Angle resolved XPS characterization of cationic polyacrylamidescitations
- 2006Defect formation and transport in La0.95Ni0.5Ti0.5O3-δcitations
- 2005Interfacial effects on the electrical properties of multiferroic BiFeO3/Pt/Si thin film heterostructurescitations
- 2005Tailoring of the PS surface with low energy ionscitations
- 2004Structural and chemical surface modification of polymers by low-energy ions and influence on nucleation, growth and adhesion of noble metals
- 2003Etching rate and structural modification of polymer films during low energy ion irradiationcitations
- 2003Mechanisms of argon ion-beam surface modification of polystyrenecitations
Places of action
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article
Tailoring of the PS surface with low energy ions
Abstract
Ion–polymer interaction induces different phenomena in the near surface layer of polymers, and promotes its adhesion to metals. Using XPS, TEM and AFM, polystyrene surface was examined after 1 keV ion-beam treatments with oxygen, nitrogen and argon ions in the ion fluence range from 1012 to 1016 cm−2 to clarify the following points: chemical reaction after treatment in vacuum and after exposure to air, identification of adsorption-relevant species for metal atoms, formation of cross-links in the outermost polymer layer. The early stages of metal–polymer interface formation during metallization play a crucial role in the metal–polymer adhesion. Therefore, the influence of the ion fluence and ion chemistry on the condensation of noble metals, film growth and peel strength were measured. The peel strength showed a maximum at a certain fluence depending on ion chemistry. For example, the surface treatment with very low fluence of oxygen ions improved the adhesion between copper and polystyrene by two orders of magnitude without significantly increasing the surface roughness measured with AFM. The locus of failure changed at the same time from interfacial failure for untreated polymer surfaces to cohesive failure in the polymer for modified surfaces. A multilayer model of the metal–polymer interface after ion treatment is suggested.