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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gkanas, Evangelos I.
Coventry University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Metal-Hydride-Based Hydrogen Storage as Potential Heat Source for the Cold Start of PEMFC in Hydrogen-Powered Coachescitations
- 2019Synthesis, characterisation and hydrogen sorption properties of mechanically alloyed Mg(Ni1-xMnx)2citations
- 2019Heat management on rectangular metal hydride tanks for green building applicationscitations
- 2018Hydrogenation behavior in rectangular metal hydride tanks under effective heat management processes for green building applicationscitations
- 2017Numerical analysis of candidate materials for multi-stage metal hydride hydrogen compression processescitations
- 2016Efficient hydrogen storage in up-scale metal hydride tanks as possible metal hydride compression agents equipped with aluminium extended surfacescitations
- 2015Numerical study on a two-stage metal hydride hydrogen compression systemcitations
- 2014Microstuctural analysis and determination of PM10 emission sources in an industrial Mediterranean citycitations
- 2013In vitro magnetic hyperthermia response of iron oxide MNP’s incorporated in DA3, MCF-7 and HeLa cancer cell linescitations
- 2013Polymer-stable magnesium nanocomposites prepared by laser ablation for efficient hydrogen storagecitations
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article
Synthesis, characterisation and hydrogen sorption properties of mechanically alloyed Mg(Ni1-xMnx)2
Abstract
Hydrogen storage materials based on the stoichiometry Mg(Ni1-xMnx)2 have been synthesized by High Energy Ball Milling (HEBM) and studied as potential candidate materials for solid state hydrogen storage. The microstructures of the as-cast and the milled alloys were characterized by means of X-ray Powder Diffraction (XRD) and Scanning Electron Microscopy (SEM) both prior and after the hydrogenation process. The storage characteristics (Pressure-Composition-Temperature isotherms) and the sorption kinetics obtained by a commercial and automatically controlled Sievert-type apparatus. The X-ray results showed that the substitution of Mn over Ni could eliminate and inhibit the MgNi2 phase. The calculation of the average crystallite size showed that the increase of the amount of Mn can reduce the size at the early stages, but for Mn content higher than 0.25 the crystallite size increases, while the microstrain levels decreased monotonically. The hydrogenation and dehydrogenation measurements took place at several temperatures (150–200–250–300 °C). The results showed that the kinetics for both the hydrogenation and dehydrogenation can be fast for operation at temperatures between 250 and 300 °C, but for temperatures below 200 °C the hydrogenation process is very slow, and the dehydrogenation process cannot be achieved.