• Sonar, Prasanat
• Ramamoorthy, Muthumareeswaran
• Chandar, N. Krishna
• Ahamed, Maqusood
• Rajeev, Priyada V.
• Grace, Andrews Nirmala
• Gothandapani, Kannan
• Jacob, George
• Pitchaimuthu, Sudhagar
• Jeong, Soon Kwan
• Raghavan, Vimala
• Sellappan, Raja
• Gnanasekar, Subashini
• Pandiaraj, Saravanan

Abstract

<p>The unique category of transition metal nitrides has an immense scope as an electron-driven catalyst in redox reactions. However, synthesizing metal nitrides without contamination is very challenging. The residues present in the catalyst might affect catalytic activity. This work reports a simple synthesis of contamination-free nanoscale molybdenum nitride (Mo₂N) powder by integrated wet chemical and thermal decomposition techniques at 800 ̊°C. Systematic structural and morphological studies were done, which shows the spherical shape of γ -Mo₂N nanoparticles. Electrochemical and photovoltaic characteristics were studied using cyclic voltammetry, electrochemical impedance spectroscopy (EIS), Tafel polarization and J–V characteristics. As a result of high electrolyte diffusivity, less charge transfer resistance, high electrochemical stability and catalytic activity, the nano Mo₂N based DSSCs exhibits 5.3 % efficiency, which is comparable to Pt-based device (6.4 %) fabricated under the similar condition that is 83.7 % of the performance offered by an expensive counter electrode. This simple synthesis method could enable low-cost mass production of Mo₂N nanoparticles as counter electrodes in DSSC. The developed counter electrodes may be a suitable alternative for stable, efficient and low-cost DSSCs.</p>

Topics

• nanoparticle
• molybdenum
• laser emission spectroscopy
• nitride
• electrochemical-induced impedance spectroscopy
• diffusivity
• thermal decomposition
• cyclic voltammetry