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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Strunskus, Thomas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Early-stage silver growth during sputter deposition on SiO2 and polystyrene - Comparison of biased DC magnetron sputtering, high-power impulse magnetron sputtering (HiPIMS) and bipolar HiPIMScitations
- 2024Early-stage silver growth during sputter deposition on SiO$_2$ and polystyrene – Comparison of biased DC magnetron sputtering, high-power impulse magnetron sputtering (HiPIMS) and bipolar HiPIMScitations
- 2024Influence of Silsesquioxane-Containing Ultra-Thin Polymer Films on Metal Oxide Gas Sensor Performance for the Tunable Detection of Biomarkerscitations
- 2024Co‐sputtering of A Thin Film Broadband Absorber Based on Self‐Organized Plasmonic Cu Nanoparticlescitations
- 2024Plasma‐Driven Tuning of Dielectric Permittivity in Graphenecitations
- 2023Two-in-One Sensor Based on PV4D4-Coated TiO 2 Films for Food Spoilage Detection and as a Breath Marker for Several Diseasescitations
- 2023Co‐sputtering of A Thin Film Broadband Absorber Based on Self‐Organized Plasmonic Cu Nanoparticles
- 2023Tuning the Selectivity of Metal Oxide Gas Sensors with Vapor Phase Deposited Ultrathin Polymer Thin Filmscitations
- 2022A thin-film broadband perfect absorber based on plasmonic copper nanoparticlescitations
- 2022In Situ Monitoring of Scale Effects on Phase Selection and Plasmonic Shifts during the Growth of AgCu Alloy Nanostructures for Anticounterfeiting Applicationscitations
- 2022Template-Induced Growth of Sputter-Deposited Gold Nanoparticles on Ordered Porous TiO$_2$ Thin Films for Surface-Enhanced Raman Scattering Sensorscitations
- 2022Sensing performance of CuO/Cu2O/ZnOcitations
- 2021Selective Silver Nanocluster Metallization on Conjugated Diblock Copolymer Templates for Sensing and Photovoltaic Applicationscitations
- 2021Tuning wettability of TiO 2 thin film by photocatalytic deposition of 3D flower- and hedgehog-like Au nano- and microstructurescitations
- 2021Revealing the growth of copper on polystyrene- block -poly(ethylene oxide) diblock copolymer thin films with in situ GISAXScitations
- 2021Tuning wettability of TiO2 thin film by photocatalytic deposition of 3D flower- and hedgehog-like Au nano- and microstructurescitations
- 2021Real-time insight into nanostructure evolution during the rapid formation of ultra-thin gold layers on polymerscitations
- 2020Following in Situ the Deposition of Gold Electrodes on Low Band Gap Polymer Filmscitations
- 2019Correlating Nanostructure, Optical and Electronic Properties of Nanogranular Silver Layers during Polymer-Template-Assisted Sputter Depositioncitations
- 2019PANI film on carbon nanowalls: synthesis and analysis
- 2019PANI film on carbon nanowalls: synthesis and analysis
- 2019The impact of O2/Ar ratio on morphology and functional properties in reactive sputtering of metal oxide thin filmscitations
- 2019Pathways to Tailor Photocatalytic Performance of TiO2 Thin Films Deposited by Reactive Magnetron Sputteringcitations
- 2018A Flexible Oxygenated Carbographite Nanofilamentous Buckypaper as an Amphiphilic Membranecitations
- 2018Plasma based formation and deposition of metal and metal oxide nanoparticles using a gas aggregation sourcecitations
- 2017Role of Sputter Deposition Rate in Tailoring Nanogranular Gold Structures on Polymer Surfacescitations
- 2015Real-Time Monitoring of Morphology and Optical Properties during Sputter Deposition for Tailoring Metal–Polymer Interfacescitations
- 2014In situ Raman spectroscopy for growth monitoring of vertically aligned multiwallcarbon nanotubes in plasma reactorcitations
- 2013Electronic structure, adsorption geometry, and photoswitchability of azobenzene layers adsorbed on layered crystalscitations
- 2012Vapour phase deposition of highly crystalline self-poled piezoelectric nylon-11citations
- 2010Anomalous Surface Compositions of Stoichiometric Mixed Oxide Compoundscitations
- 2008Tuning of electrical and structural properties of metal-polymer nanocomposite films prepared by co-evaporation techniquecitations
- 2007Influence of molecular structure on phase transitions: A study of self-assembled monolayers of 2-(aryl)-ethane thiolscitations
Places of action
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article
Sensing performance of CuO/Cu2O/ZnO
Abstract
Gas sensors are demanded in many different application fields. Especially the ever-growing field of batteries creates a great need for early hazard detection by gas sensors. Metal oxides are well known for gas sensing; however, moisture continues to be a major problem for the sensors, especially for the application in battery systems. This study reports on a new type of moisture protected gas sensor, which is capable to solve this problem. Sensitive nano-materials of CuO/Cu2O/ZnO:Fe heterostructures are grown and subsequently coated with an ultrathin hydrophobic cyclosiloxane-polymer film via initiated chemical vapor deposition to protect the sensor from moisture. The monomer 1,3,5-trimethyl-1,3,5-trivinylcyclotrisiloxane is combined with the initiator perfluorobutanesulfonyl fluoride to obtain hydrophobic properties. Surface chemistry, film formation and preservation of functional groups are confirmed by X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy. It turns out that the hydrophobicity is retained even after annealing at 400 °C, which is ideal for gas sensing. Molecular distances in the polymer nanolayer are estimated by geometry optimization via MMFF94 followed by density functional theory. Compared with unprotected CuO/Cu2O/ZnO:Fe, the coated CuO/Cu2O/ZnO:Fe exhibit a much better sensing performance at a higher relative humidity, as well as tunability of the gas selectivity. This is highly beneficial for hazard detection in case of thermal runaway in batteries because the sensors can be used under high concentrations of relative humidity, which is ideal for Li–S battery applications.