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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Baniasadi, Hossein
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Polypyrrole-modified flax fiber sponge impregnated with fatty acids as bio-based form-stable phase change materials for enhanced thermal energy storage and conversioncitations
- 2024Polypyrrole-modified flax fiber sponge impregnated with fatty acids as bio-based form-stable phase change materials for enhanced thermal energy storage and conversioncitations
- 2024Fabrication of biocomposite materials with polycaprolactone and activated carbon extracted from agricultural wastecitations
- 2024Exploring the potential of regenerated Ioncell fiber composites: a sustainable alternative for high-strength applicationscitations
- 2024Elucidating the enduring transformations in cellulose-based carbon nanofibers through prolonged isothermal treatmentcitations
- 2024Wood flour and Kraft lignin enable air-drying of the nanocellulose-based 3D-printed structurescitations
- 2024Recycled carbon fiber reinforced composites: Enhancing mechanical properties through co-functionalization of carbon nanotube-bonded microfibrillated cellulosecitations
- 2024A cradle-to-gate life cycle assessment of polyamide-starch biocomposites: carbon footprint as an indicator of sustainabilitycitations
- 2023Strontium-Substituted Nanohydroxyapatite-Incorporated Poly(lactic acid) Composites for Orthopedic Applications: Bioactive, Machinable, and High-Strength Propertiescitations
- 2023Flexible and conductive nanofiber textiles for leakage-free electro-thermal energy conversion and storagecitations
- 2023Heat-Induced Actuator Fibers: Starch-Containing Biopolyamide Composites for Functional Textilescitations
- 2023High-concentration lignin biocomposites with low-melting point biopolyamidecitations
- 2023Innovative integration of pyrolyzed biomass into polyamide 11: Sustainable advancements through in situ polymerization for enhanced mechanical, thermal, and additive manufacturing propertiescitations
- 2021Exfoliated clay nanocomposites of renewable long-chain aliphatic polyamide through in-situ polymerizationcitations
- 2021Sustainable composites of surface-modified cellulose with low-melting point polyamidecitations
- 2021Novel long-chain aliphatic polyamide/surface-modified silicon dioxide nanocomposites: in-situ polymerization and propertiescitations
- 2021Alginate/cartilage extracellular matrix-based injectable interpenetrating polymer network hydrogel for cartilage tissue engineeringcitations
- 2021Selective Laser Sintering of Lignin-Based Compositescitations
- 20213D-Printed Thermoset Biocomposites Based on Forest Residues by Delayed Extrusion of Cold Masterbatch (DECMA)citations
- 2021High-Performance and Biobased Polyamide/Functionalized Graphene Oxide Nanocomposites through In Situ Polymerization for Engineering Applicationscitations
- 2015Investigation of thermomechanical properties of UHMWPE/graphene oxide nanocomposites prepared by in situ Ziegler–Natta polymerizationcitations
Places of action
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article
Novel long-chain aliphatic polyamide/surface-modified silicon dioxide nanocomposites: in-situ polymerization and properties
Abstract
A new kind of long-chain aliphatic polyamide (PA1218) with a relatively low melting point, high molecular weight, and stable mechanical properties at humid conditions was successfully developed via a polycondensation reaction between 1,18-octadecanedioic acid and 1,12-diaminodecane. Additionally, oleic acid-surfaced modified silicon dioxide (SSD) was prepared and employed to improve the properties of PA1218 through in-situ polymerization. FT-IR spectra and TGA thermograms confirmed the successful surface modification of nanoparticles, and consequently, 5% substitution of surface hydroxyl groups of SiO2 nanoparticles with oleic acid molecules. Moreover, the thermomechanical and rheology tests revealed a significant improvement in nanocomposites’ properties compared to the pure PA1218; for instance, the tensile strength and storage modulus were increased by 22% and 40%, respectively in the sample containing 3% SSD nanoparticles. This improvement, along with SEM images, confirmed the uniform dispersion of SSD nanoparticles through the employed in-situ polymerization and excellent compatibility between inorganic and organic phases, which was achieved via surface modification. Finally, all the samples demonstrated a water uptake capacity of less than 0.6% attributed to the high methylene/amide ratio in their backbones, causing these newly developed nanocomposites to be notable candidates for specific engineering applications.