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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Chen, Zhuo
Erich Schmid Institute of Materials Science
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Structural Characterization of La0.6Sr0.4CoO3-δ Thin Films Grown on (100)-, (110)-, and (111)-Oriented La0.95Sr0.05Ga0.95Mg0.05O3-δ
- 2024Experimental study and numerical simulation of adhesively bonded timber-concrete composite panels: bending behavior, adhesive shear and peel stress distributionscitations
- 2023Bending behavior and bond analysis on adhesively bonded glulam-concrete panels fabricated with wet bonding techniquecitations
- 2023Large mechanical properties enhancement in ceramics through vacancy-mediated unit cell disturbancecitations
- 2023Enhancing Organic Semiconductor Molecular Packing Using Perovskite Interfaces to Improve Singlet Fissioncitations
- 2023Short-range order patterns in Mg66Zn29Ca5 metallic glasscitations
- 2022Atomistic mechanisms underlying plasticity and crack growth in ceramics : a case study of AlN/TiN superlatticescitations
- 2022Surmounting the thermal processing limitscitations
Places of action
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article
Surmounting the thermal processing limits
Abstract
<p>Ni-free Ti-based bulk metallic glasses (BMGs) are promising for biomedical applications, thanks to their excellent biocompatibility and high corrosion resistance. BMGs can be shaped and patterned by viscous flow deformation using thermoplastic net-shaping. This work presents a novel strategy for thermoplastic net-shaping of Ti<sub>40</sub>Zr<sub>10</sub>Cu<sub>34</sub>Pd<sub>14</sub>Sn<sub>2</sub> BMG. Instead of operating for a short time slightly above the glass transition temperature to avoid crystallization, the proposed method accepts the formation of nanocrystals and makes use of the lower viscosity of the supercooled liquid when processing above the glass transition temperature. Following this approach, Ti<sub>40</sub>Zr<sub>10</sub>Cu<sub>34</sub>Pd<sub>14</sub>Sn<sub>2</sub> BMG is deformed from a rod to a thin disk, and patterns scaling from 5 μm to 300 μm are successfully created on the Ti-BMG surfaces, demonstrating the potential to create complex features for functional materials. Furthermore, after the thermoplastic net-shaping treatment, the Vickers hardness increases by 6% while the corrosion and passivation current density decrease by an order of magnitude. This work reveals that the BMGs can still be deformed and patterned via the thermoplastic net-shaping technique if the first crystallization event of the BMG systems is the formation of nanocrystals. Most importantly, this work reveals the possibility of processing a broad family of mediocre glass-forming systems and semi-crystalline composites via thermoplastic net-shaping.</p>