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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Taylor, Mark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024In-situ Heating-Stage EBSD Validation of Algorithms for Prior Austenite Grain Reconstruction in Steelcitations
- 2024Heat Treatment Optimisation of Electron Beam Welded Reactor Pressure Vessel Steel
- 2023A Rapid, Open-Source CCT Predictor for Low-Alloy Steels, and Its Application to Compositionally Heterogeneous Materialcitations
- 2023Dynamic Precipitation in Supersaturated Al–Zn–Mg–Cu Alloy During Warm Stretchingcitations
- 2022The Effect of Compositional Heterogeneity on the Martensite Start Temperature of a High Strength Steel During Rapid Austenitisation and Coolingcitations
- 2019Interaction of a tripeptide with titania surfaces: RGD adsorption on rutile TiO2(110) and model dental implant surfacescitations
- 2017Investigation of the influence of heat balance shifts on the freeze microstructure and composition in aluminum smelting bath system: Cryolite-CaF2-AlF3-Al2O3citations
- 2011Predicting wear of UHMWPE: decreasing wear rate following a change in directioncitations
- 2010Verification of Predicted Knee Replacement Kinematics During Simulated Gait in the Kansas Knee Simulatorcitations
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article
Interaction of a tripeptide with titania surfaces: RGD adsorption on rutile TiO2(110) and model dental implant surfaces
Abstract
The adsorption of peptides on metal oxides is an area of significant interest, both fundamentally and in a number of technologically important areas. These range from the integration of biomaterials in the body, to denaturation of protein therapeutics and the use of biomolecules and bioinspired materials in synthesis and stabilization of novel nanomaterials. Here we present a study of the tripeptide arginylglycylaspartic acid (RGD) on the surfaces of vacuum-prepared single crystalline TiO2(110), pyrocatechol-capped TiO2(110), and model SLA and SLActive dental implant samples. X-ray Photoelectron Spectroscopy and Scanning Tunneling Microscopy show that the RGD adsorption mode on the single crystal is consistent with bonding through the deprotonated carboxylate groups of the peptide to surface Ti atoms of the substrate. Despite the increased hydrophobicity of the pyrocatechol-capped TiO2(110) surface RGD adsorption from solution increases following this surface treatment. RGD adsorption on SLA and SLActive surfaces shows that the SLActive surface has a greater uptake of RGD. The RGD uptake on the pyrocatechol capped single crystal and the model implant surfaces suggest that the ease with which surface contaminant hydrocarbons are removed from the surface has a greater influence on peptide adsorption than hydrophobicity/hydrophilicity of the surface.