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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gunputh, Urvashi Fowdar
University of Derby
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Comparing Bio-Ester and Mineral-Oil Emulsions on Tool Wear and Surface Integrity in Finish Turning a Ni-Based Superalloycitations
- 2024Orientation effects on the fracture behaviour of additively manufactured stainless steel 316L subjected to high cyclic fatiguecitations
- 2023Effect of Grain Structure on Machinability of LPBF Inconel 718: A Critical Reviewcitations
- 2023Effect of Powder Bed Fusion Laser Sintering on Dimensional Accuracy and Tensile Properties of Reused Polyamide 11citations
- 2021Selective laser melting of a high precision turbomachinery application in IN718 alloy
- 2021High strain rate effect on tensile ductility and fracture of AM fabricated Inconel 718 with voided microstructurescitations
- 2021High strain rate effect on tensile ductility and fracture of AM fabricated Inconel 718 with voided microstructurescitations
- 2021Analysis of machining performance of Inconel 718 printed by PBF-LM (powder bed fusion laser melting)
- 2020Effect of element wall thickness on the homogeneity and isotropy of hardness in SLM IN718 using nanoindentationcitations
- 2020Effect of powder bed fusion laser melting process parameters, build orientation and strut thickness on porosity, accuracy and tensile properties of an auxetic structure in IN718 alloycitations
- 2020A review of in-situ grown nanocomposite coatings for titanium alloy implantscitations
- 2018Antibacterial Properties of TiO2 Nanotubes coated with nano-ZnO and nano-Ag
- 2018Anodised TiO 2 nanotubes as a scaffold for antibacterial silver nanoparticles on titanium implants.citations
Places of action
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article
Anodised TiO 2 nanotubes as a scaffold for antibacterial silver nanoparticles on titanium implants.
Abstract
Medical grade titanium alloy is widely used for bone/dental implants, but the material alone has no innate antimicrobial properties that would reduce infection risk following surgery. However, silver nanoparticles (Ag NPs) are known to be antibacterial. This study investigated the growth of Ag NPs on titanium dioxide nanotubes (TiO2 NTs) on Ti-6Al-4V discs. The TiO2 NTs were grown on the Ti alloy using an electrochemical method, and then decorated with Ag NPs. The Ag NPs were synthesised by chemical reduction using δ-gluconolactone. A silver ammonia solution (silver nitrate + liquid ammonia) was used as the source of silver. Two separate approaches were used: (1) The δ-gluconolactone was mixed with the silver ammonia and then exposed to the TiO2 NTs (the ‘mixing method’), which produced micron-sized clusters of the Ag NPs. (2) The TiO2 NTs were exposed to the silver ammonia first and then to δ-gluconolactone (the ‘sequential addition method’), which resulted in the formation of nano-sized clusters of the nanoparticles. The Ag-TiO2 composites were confirmed by scanning electron microscopy and the elements analysed using energy dispersive X-ray spectroscopy (EDS). The composite coatings were exposed to a simulated body fluid for 24 h in order to determine the total Ag released. The release from the micron-sized clusters from the mixing method (14.6 ± 0.67 ppm) was higher than that from the nano-sized clusters (4.05 ± 0.36 ppm) when 0.015 M of silver ammonia was used. Additionally, Staphylococcus aureus, was cultured on the composite coatings for 24 h. Both the micron- and nano-sized clusters of the Ag NPs were found to be antibacterial using the Live/Dead assay. Overall, δ-gluconolactone was successfully used to reduce silver to Ag NPs on the surface of TiO2 NTs. The sequential addition method was the preferred method of synthesis because of its slower silver release, better coverage of the Ag-NPs on the TiO2 NTs and strong antibacterial properties.