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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jaroszewicz, Jakub
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2023In vitro and in vivo degradation behavior of Mg-0.45Zn-0.45Ca (ZX00) screws for orthopedic applicationscitations
- 2023How to control the crystallization of metallic glasses during laser powder bed fusion? Towards part-specific 3D printing of in situ compositescitations
- 2023In-depth analysis of the influence of bio-silica filler (Didymosphenia geminata frustules) on the properties of Mg matrix compositescitations
- 2022A comparison of the microstructure-dependent corrosion of dual-structured Mg-Li alloys fabricated by powder consolidation methods: Laser powder bed fusion vs pulse plasma sinteringcitations
- 2022Effect of annealing on the mechanical and corrosion properties of 316L stainless steel manufactured by laser powder bed fusioncitations
- 2022Novel optical photothermal infrared (O-PTIR) spectroscopy for the noninvasive characterization of heritage glass-metal objectscitations
- 2022How to Control the Crystallization of Metallic Glasses During Laser Powder Bed Fusion? Towards Part-Specific 3d Printing of in Situ Composites
- 2021Ultrashort Sintering and Near Net Shaping of Zr-Based AMZ4 Bulk Metallic Glasscitations
- 2020Surface sintering of tungsten powder targets designed by electromagnetic discharge: A novel approach for film synthesis in magnetron sputteringcitations
- 2020Analysis of Microstructure and Properties of a Ti–AlN Composite Produced by Selective Laser Meltingcitations
- 2020Functionalization of 3D Chitinous Skeletal Scaffolds of Sponge Origin Using Silver Nanoparticles and Their Antibacterial Propertiescitations
- 2019Microstructure and corrosion resistance of warm sprayed titanium coatings with polymer sealing for corrosion protection of AZ91E magnesium alloycitations
- 2019Corrosion Resistance of Aluminum Coatings Deposited by Warm Spraying on AZ91E Magnesium Alloycitations
- 20193D bioprinting of hydrogel constructs with cell and material gradients for the regeneration of full-thickness chondral defect using a microfluidic printing headcitations
- 2019Engineering Human-Scale Artificial Bone Grafts for Treating Critical-Size Bone Defectscitations
- 2018Micro and nanoscale characterization of poly(DL-lactic-co-glycolic acid) films subjected to the L929 cells and the cyclic mechanical loadcitations
- 2016In vitro degradation of ZM21 magnesium alloy in simulated body fluidscitations
- 2016Characterization of three-dimensional printed composite scaffolds prepared with different fabrication methodscitations
- 2015Influence of the Al (Co, Ni) layer on the corrosion resistance of a cobalt based alloy (Mar-M-509®)citations
- 2013Investigation of degradation mechanism of palladium-nickel wires during oxidation of ammoniacitations
- 2006Nanocrystalline Cemented Carbides Sintered by the Pulse Plasma Methodcitations
- 2006Nanocrystalline Cu-Al2O3 Composites Sintered by the Pulse Plasma Techniquecitations
- 2006NiAl–Al2O3 composites produced by pulse plasma sintering with the participation of the SHS reactioncitations
Places of action
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article
In vitro degradation of ZM21 magnesium alloy in simulated body fluids
Abstract
In vitro degradation behavior of squeeze cast (CAST) and equal channel angular pressed (ECAP) ZM21 magnesium alloy (2.0 wt% Zn-0.98 wt% Mn) was studied using immersion tests up to 4 w in three different biological environments. Hanks' Balanced Salt Solution (Hanks), Earle's Balanced Salt Solution (Earle) and Eagle minimum essential medium supplemented with 10% (v/v) fetal bovine serum (E-MEM + 10% FBS) were used to investigate the effect of carbonate buffer system, organic compounds and material processing on the degradation behavior of the ZM21 alloy samples. Corrosion rate of the samples was evaluated by their Mg2 + ion release, weight loss and volume loss. In the first 24 h, the corrosion rate sequence of the CAST samples was as following: Hanks > E-MEM + 10% FBS > Earle. However, in longer immersion periods, the corrosion rate sequence was Earle > E-MEM + 10% FBS ≥ Hanks. Strong buffering effect provided by carbonate buffer system helped to maintain the pH avoiding drastic increase of the corrosion rate of ZM21 in the initial stage of immersion. Organic compounds also contributed to maintain the pH of the fluid. Moreover, they adsorbed on the sample surface and formed an additional barrier on the insoluble salt layer, which was effective to retard the corrosion of CAST samples. In case of ECAP, however, this effect was overcome by the occurrence of strong localized corrosion due to the lower pH of the medium. Corrosion of ECAP samples was much greater than that of CAST, especially in Hanks, due to higher sensitivity of ECAP to localized corrosion and the presence of Cl−. The present work demonstrates the importance of using an appropriate solution for a reliable estimation of the degradation rate of Mg-base degradable implants in biological environments, and concludes that the most appropriate solution for this purpose is E-MEM + 10% FBS, which has the closest chemical composition to human blood plasma.